Bimetallic lanthanide complexes derived from macrocycle-appended m-xylyl derivatives: Synthesis and spectroscopic properties

Matteo P. Placidi; Louise S. Natrajan; Daniel Sykes; Alan M. Kenwright; Stephen Faulkner

doi:10.1002/hlca.200900141

Bimetallic lanthanide complexes derived from macrocycle-appended m-xylyl derivatives: Synthesis and spectroscopic properties

Matteo P. Placidi, Louise S. Natrajan, Daniel Sykes, Alan M. Kenwright, Stephen Faulkner

Research output: Contribution to journal › Article › peer-review

Abstract

A series of bimetallic lanthanide complexes was prepared from a bimacrocyclic system in which two DO3A units are linked by a m-xylyl unit appended with either a NO2 or an NH2 group (DO3A=1,4,7,10-tetraazacyclododecane-1,4,7-triacetic acid). The Nd-, Eu-, Tb- and Yb-complexes were all luminescent: time-resolved studies indicated that the lipophilic xylyl group restricts close approach of H2O to the metal centre. © 2009 Verlag Helvetica Chimica Acta AG.

Original language	English
Pages (from-to)	2427-2438
Number of pages	11
Journal	Helvetica Chimica Acta
Volume	92
Issue number	11
DOIs	https://doi.org/10.1002/hlca.200900141
Publication status	Published - Nov 2009

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CCDC 728845: Experimental Crystal Structure Determination
Placidi, M. P. (Contributor), Natrajan, L. (Contributor), Sykes, D. (Contributor), Kenwright, A. M. (Contributor) & Faulkner, S. (Contributor), Cambridge Crystallographic Data Centre, 1 Jan 2011
DOI: 10.5517/ccsgf4s, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/ccsgf4s&sid=DataCite
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title = "Bimetallic lanthanide complexes derived from macrocycle-appended m-xylyl derivatives: Synthesis and spectroscopic properties",

abstract = "A series of bimetallic lanthanide complexes was prepared from a bimacrocyclic system in which two DO3A units are linked by a m-xylyl unit appended with either a NO2 or an NH2 group (DO3A=1,4,7,10-tetraazacyclododecane-1,4,7-triacetic acid). The Nd-, Eu-, Tb- and Yb-complexes were all luminescent: time-resolved studies indicated that the lipophilic xylyl group restricts close approach of H2O to the metal centre. {\textcopyright} 2009 Verlag Helvetica Chimica Acta AG.",

author = "Placidi, {Matteo P.} and Natrajan, {Louise S.} and Daniel Sykes and Kenwright, {Alan M.} and Stephen Faulkner",

year = "2009",

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T1 - Bimetallic lanthanide complexes derived from macrocycle-appended m-xylyl derivatives: Synthesis and spectroscopic properties

AU - Placidi, Matteo P.

AU - Natrajan, Louise S.

AU - Sykes, Daniel

AU - Kenwright, Alan M.

AU - Faulkner, Stephen

PY - 2009/11

Y1 - 2009/11

N2 - A series of bimetallic lanthanide complexes was prepared from a bimacrocyclic system in which two DO3A units are linked by a m-xylyl unit appended with either a NO2 or an NH2 group (DO3A=1,4,7,10-tetraazacyclododecane-1,4,7-triacetic acid). The Nd-, Eu-, Tb- and Yb-complexes were all luminescent: time-resolved studies indicated that the lipophilic xylyl group restricts close approach of H2O to the metal centre. © 2009 Verlag Helvetica Chimica Acta AG.

AB - A series of bimetallic lanthanide complexes was prepared from a bimacrocyclic system in which two DO3A units are linked by a m-xylyl unit appended with either a NO2 or an NH2 group (DO3A=1,4,7,10-tetraazacyclododecane-1,4,7-triacetic acid). The Nd-, Eu-, Tb- and Yb-complexes were all luminescent: time-resolved studies indicated that the lipophilic xylyl group restricts close approach of H2O to the metal centre. © 2009 Verlag Helvetica Chimica Acta AG.

U2 - 10.1002/hlca.200900141

DO - 10.1002/hlca.200900141

M3 - Article

SN - 1522-2675

VL - 92

SP - 2427

EP - 2438

JO - Helvetica Chimica Acta

JF - Helvetica Chimica Acta

IS - 11

ER -

Bimetallic lanthanide complexes derived from macrocycle-appended m-xylyl derivatives: Synthesis and spectroscopic properties

Abstract

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CCDC 728845: Experimental Crystal Structure Determination

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