Bis(acetylacetonato-κ2 O,O′)[copper(II)nickel(II)(0. 31/0.69)]: A mixed-metal complex

Muhammad Shahid; Mazhar Hamid; Muhammad Mazhar; Mohammad Azad Malik; James Raftery

doi:10.1107/S160053681002756X

Bis(acetylacetonato-κ2 O,O′)[copper(II)nickel(II)(0. 31/0.69)]: A mixed-metal complex

Muhammad Shahid^*, Mazhar Hamid, Muhammad Mazhar, Mohammad Azad Malik, James Raftery

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

Abstract

The title complex, [Cu_0.31Ni_0.69(C₅H ₇O₂)₂], was isolated from the reaction of bis(N,N-dimethyaminoethanol)copper(II) with bis(acetylacetonato)nickel(II), which yielded crystals with mixed sites at the central metal position; the refined copper-nickel occupancy ratio is 0.31 (4):0.69 (4). Two acetylacetonate ligands, related by a centre of symmetry, are coordinated to the central metal atom in a square-planar configuration while the methyne C atoms of the acetylacetonate ligands, ca 3.02 Å away, are orthogonal to this plane at the metal site.

Original language	English
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	66
Issue number	8
DOIs	https://doi.org/10.1107/S160053681002756X
Publication status	Published - 1 Aug 2010

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10.1107/S160053681002756X

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title = "Bis(acetylacetonato-κ2 O,O′)[copper(II)nickel(II)(0. 31/0.69)]: A mixed-metal complex",

abstract = "The title complex, [Cu0.31Ni0.69(C5H 7O2)2], was isolated from the reaction of bis(N,N-dimethyaminoethanol)copper(II) with bis(acetylacetonato)nickel(II), which yielded crystals with mixed sites at the central metal position; the refined copper-nickel occupancy ratio is 0.31 (4):0.69 (4). Two acetylacetonate ligands, related by a centre of symmetry, are coordinated to the central metal atom in a square-planar configuration while the methyne C atoms of the acetylacetonate ligands, ca 3.02 {\AA} away, are orthogonal to this plane at the metal site.",

author = "Muhammad Shahid and Mazhar Hamid and Muhammad Mazhar and {Azad Malik}, Mohammad and James Raftery",

year = "2010",

month = aug,

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language = "English",

volume = "66",

journal = "Acta Crystallographica Section E: Structure Reports Online",

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TY - JOUR

T1 - Bis(acetylacetonato-κ2 O,O′)[copper(II)nickel(II)(0. 31/0.69)]

T2 - A mixed-metal complex

AU - Shahid, Muhammad

AU - Hamid, Mazhar

AU - Mazhar, Muhammad

AU - Azad Malik, Mohammad

AU - Raftery, James

PY - 2010/8/1

Y1 - 2010/8/1

N2 - The title complex, [Cu0.31Ni0.69(C5H 7O2)2], was isolated from the reaction of bis(N,N-dimethyaminoethanol)copper(II) with bis(acetylacetonato)nickel(II), which yielded crystals with mixed sites at the central metal position; the refined copper-nickel occupancy ratio is 0.31 (4):0.69 (4). Two acetylacetonate ligands, related by a centre of symmetry, are coordinated to the central metal atom in a square-planar configuration while the methyne C atoms of the acetylacetonate ligands, ca 3.02 Å away, are orthogonal to this plane at the metal site.

AB - The title complex, [Cu0.31Ni0.69(C5H 7O2)2], was isolated from the reaction of bis(N,N-dimethyaminoethanol)copper(II) with bis(acetylacetonato)nickel(II), which yielded crystals with mixed sites at the central metal position; the refined copper-nickel occupancy ratio is 0.31 (4):0.69 (4). Two acetylacetonate ligands, related by a centre of symmetry, are coordinated to the central metal atom in a square-planar configuration while the methyne C atoms of the acetylacetonate ligands, ca 3.02 Å away, are orthogonal to this plane at the metal site.

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U2 - 10.1107/S160053681002756X

DO - 10.1107/S160053681002756X

M3 - Article

AN - SCOPUS:77956864141

SN - 1600-5368

VL - 66

JO - Acta Crystallographica Section E: Structure Reports Online

JF - Acta Crystallographica Section E: Structure Reports Online

IS - 8

ER -

Bis(acetylacetonato-κ2 O,O′)[copper(II)nickel(II)(0. 31/0.69)]: A mixed-metal complex

Abstract

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CCDC 788239: Experimental Crystal Structure Determination

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Bis(acetylacetonato-κ2 O,O′)[copper(II)nickel(II)(0. 31/0.69)]: A mixed-metal complex

Abstract

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Datasets

CCDC 788239: Experimental Crystal Structure Determination

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