Carboxylation of Phenols with CO2 at Atmospheric Pressure

Junfei Luo; Sara Preciado; Pan Xie; Igor Larrosa

doi:10.1002/chem.201601114

Carboxylation of Phenols with CO2 at Atmospheric Pressure

Junfei Luo^*, Sara Preciado, Pan Xie, Igor Larrosa

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

Abstract

A convenient and efficient method for the ortho-carboxylation of phenols under atmospheric CO₂ pressure has been developed. This method provides an alternative to the previously reported Kolbe-Schmitt method, which requires very high pressures of CO₂. The addition of a trisubstituted phenol has proved essential for the successful carboxylation of phenols with CO₂ at standard atmospheric pressure, allowing the efficient preparation of a broad variety of salicylic acids.

Original language	English
Pages (from-to)	6798-6802
Number of pages	5
Journal	Chemistry - A European Journal
Volume	22
Issue number	20
DOIs	https://doi.org/10.1002/chem.201601114
Publication status	Published - 10 May 2016

Keywords

carbon dioxide
Kolbe-Schmitt reaction
phenols
salicylic acids
synthetic methods

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10.1002/chem.201601114

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abstract = "A convenient and efficient method for the ortho-carboxylation of phenols under atmospheric CO2 pressure has been developed. This method provides an alternative to the previously reported Kolbe-Schmitt method, which requires very high pressures of CO2. The addition of a trisubstituted phenol has proved essential for the successful carboxylation of phenols with CO2 at standard atmospheric pressure, allowing the efficient preparation of a broad variety of salicylic acids.",

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AU - Luo, Junfei

AU - Preciado, Sara

AU - Xie, Pan

AU - Larrosa, Igor

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N2 - A convenient and efficient method for the ortho-carboxylation of phenols under atmospheric CO2 pressure has been developed. This method provides an alternative to the previously reported Kolbe-Schmitt method, which requires very high pressures of CO2. The addition of a trisubstituted phenol has proved essential for the successful carboxylation of phenols with CO2 at standard atmospheric pressure, allowing the efficient preparation of a broad variety of salicylic acids.

AB - A convenient and efficient method for the ortho-carboxylation of phenols under atmospheric CO2 pressure has been developed. This method provides an alternative to the previously reported Kolbe-Schmitt method, which requires very high pressures of CO2. The addition of a trisubstituted phenol has proved essential for the successful carboxylation of phenols with CO2 at standard atmospheric pressure, allowing the efficient preparation of a broad variety of salicylic acids.

KW - carbon dioxide

KW - Kolbe-Schmitt reaction

KW - phenols

KW - salicylic acids

KW - synthetic methods

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ER -

Carboxylation of Phenols with CO2 at Atmospheric Pressure

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Keywords

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