Catalysis in ionic liquids

Vasile I. Pârvulescu; Christopher Hardacre

doi:10.1021/cr050948h

Catalysis in ionic liquids

Vasile I. Pârvulescu^*, Christopher Hardacre

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

Abstract

A review in the use of ionic liquids' solvents in catalyzed reactions as well as its use in biocatalytic and electrocatalyzed reactions has been presented. These reactions include hydrogenation, catalytic oxidation, acid-base-catalyzed reactions, carbonylation and hydroformylation, dimerization, polymerization, Heck reaction, Suzuki cross-coupling and other related reaction. The study clearly shows a large potential using the combination of ILs and solid catalysts in both liquid-phase and gas-phase reactions. The latter shows the versatility of ILs in stabilizing homogeneous catalysts and enables good mass transport of gas reagents using thin films of the ionic liquid.

Original language	English
Pages (from-to)	2615-2665
Number of pages	51
Journal	Chemical Reviews
Volume	107
Issue number	6
DOIs	https://doi.org/10.1021/cr050948h
Publication status	Published - Jun 2007

Access to Document

10.1021/cr050948h

Cite this

@article{4df6e996dd7845ca85f4a90407c83959,

title = "Catalysis in ionic liquids",

abstract = "A review in the use of ionic liquids' solvents in catalyzed reactions as well as its use in biocatalytic and electrocatalyzed reactions has been presented. These reactions include hydrogenation, catalytic oxidation, acid-base-catalyzed reactions, carbonylation and hydroformylation, dimerization, polymerization, Heck reaction, Suzuki cross-coupling and other related reaction. The study clearly shows a large potential using the combination of ILs and solid catalysts in both liquid-phase and gas-phase reactions. The latter shows the versatility of ILs in stabilizing homogeneous catalysts and enables good mass transport of gas reagents using thin films of the ionic liquid.",

author = "P{\^a}rvulescu, {Vasile I.} and Christopher Hardacre",

year = "2007",

month = jun,

doi = "10.1021/cr050948h",

language = "English",

volume = "107",

pages = "2615--2665",

journal = "Chemical Reviews",

issn = "0009-2665",

publisher = "American Chemical Society",

number = "6",

}

TY - JOUR

T1 - Catalysis in ionic liquids

AU - Pârvulescu, Vasile I.

AU - Hardacre, Christopher

PY - 2007/6

Y1 - 2007/6

N2 - A review in the use of ionic liquids' solvents in catalyzed reactions as well as its use in biocatalytic and electrocatalyzed reactions has been presented. These reactions include hydrogenation, catalytic oxidation, acid-base-catalyzed reactions, carbonylation and hydroformylation, dimerization, polymerization, Heck reaction, Suzuki cross-coupling and other related reaction. The study clearly shows a large potential using the combination of ILs and solid catalysts in both liquid-phase and gas-phase reactions. The latter shows the versatility of ILs in stabilizing homogeneous catalysts and enables good mass transport of gas reagents using thin films of the ionic liquid.

AB - A review in the use of ionic liquids' solvents in catalyzed reactions as well as its use in biocatalytic and electrocatalyzed reactions has been presented. These reactions include hydrogenation, catalytic oxidation, acid-base-catalyzed reactions, carbonylation and hydroformylation, dimerization, polymerization, Heck reaction, Suzuki cross-coupling and other related reaction. The study clearly shows a large potential using the combination of ILs and solid catalysts in both liquid-phase and gas-phase reactions. The latter shows the versatility of ILs in stabilizing homogeneous catalysts and enables good mass transport of gas reagents using thin films of the ionic liquid.

UR - http://www.scopus.com/inward/record.url?scp=34447098295&partnerID=8YFLogxK

U2 - 10.1021/cr050948h

DO - 10.1021/cr050948h

M3 - Article

AN - SCOPUS:34447098295

SN - 0009-2665

VL - 107

SP - 2615

EP - 2665

JO - Chemical Reviews

JF - Chemical Reviews

IS - 6

ER -

Catalysis in ionic liquids

Abstract

Access to Document

Other files and links

Fingerprint

Cite this