catena-[HgCl2([18]aneS2O4)]HgCl 2 at 150 K: A redetermination and reinterpretation

Martin Schroder, A J Blake, S Parsons, C Radek, M Schröder

    Research output: Contribution to journalArticlepeer-review

    Abstract

    The structure of the title compound {[HgCl2([18]aneS2O4)]HgCl2}n ([18]aneS2O4 = 1,4,7,10-tetraoxa-13,16-dithiacyclooctadecane), [Hg2Cl4(C12H24O4S2)], has been redetermined, and reinterpreted as a one-dimensional polymeric thread comprising linked Hg4Cl4 macrocyclic moieties with pendant macrocyclic ligands. {the compound may be named catena-poly[(chloromercury)-di-[mu]-chloro-bis[(1,4,7,10-tetraoxa-13,16-di-thiacyclooctadecane-S,S)mercury]-di-[mu]-chloro-(chloromercury)-di-[mu]-chloro]}.
    Original languageEnglish
    Pages (from-to)21-24
    Number of pages4
    JournalActa Crystallographica. Section C: Structural Chemistry
    Volume52
    Issue number1
    DOIs
    Publication statusPublished - 1996

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