C–H Borylation: No Need to Stop for Directions

Hugh C. Osborne, Alastair Durie, Christine K. Schmidt, Igor Larrosa

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Abstract

A recent work by Hartwig et al. (Science, 2020) details an efficient method to borylate strong primary C(sp3)–H bonds via iridium-catalysed C–H activation. The conditions confer counterintuitive selectivity over more labile C–H bonds, while providing an avenue for a gamut of synthetically valuable late-stage functionalisations through versatile borylate intermediates.
Original languageEnglish
JournalTrends in Chemistry
Early online date17 Aug 2020
DOIs
Publication statusE-pub ahead of print - 17 Aug 2020

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