Characterization and orientation of adsorbed NO dimers on Ag{111} at low temperatures

W. A. Brown; P. Gardner; M. Perez Jigato; D. A. King

Characterization and orientation of adsorbed NO dimers on Ag{111} at low temperatures

W. A. Brown, P. Gardner, M. Perez Jigato, D. A. King

Research output: Contribution to journal › Article › peer-review

Abstract

Reflection-absorption infrared spectroscopy (RAIRS) and near-edge x-ray absorption fine structure (NEXAFS) have been used, with isotopic 14NO/15NO mixtures, to determine the structure and orientation of the monolayer species formed by NO adsorption on Ag{111} at 40 to 60 K. The adlayer is composed of NO dimers bonded with the N-N axis in the surface plane and with the molecular plane tilted away from the surface normal by about 30°. This structure provides a simple basis for understanding the facile reaction to adsorbed N2O and O which occurs on heating to 70 to 90 K. © 1995 American Institute of Physics.

Original language	English
Pages (from-to)	7277-7280
Number of pages	3
Journal	Journal of Chemical Physics
Volume	102
Issue number	18
Publication status	Published - 1995

Cite this

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title = "Characterization and orientation of adsorbed NO dimers on Ag{111} at low temperatures",

abstract = "Reflection-absorption infrared spectroscopy (RAIRS) and near-edge x-ray absorption fine structure (NEXAFS) have been used, with isotopic 14NO/15NO mixtures, to determine the structure and orientation of the monolayer species formed by NO adsorption on Ag{111} at 40 to 60 K. The adlayer is composed of NO dimers bonded with the N-N axis in the surface plane and with the molecular plane tilted away from the surface normal by about 30°. This structure provides a simple basis for understanding the facile reaction to adsorbed N2O and O which occurs on heating to 70 to 90 K. {\textcopyright} 1995 American Institute of Physics.",

author = "Brown, {W. A.} and P. Gardner and {Perez Jigato}, M. and King, {D. A.}",

year = "1995",

language = "English",

volume = "102",

pages = "7277--7280",

journal = "Journal of Chemical Physics",

issn = "0021-9606",

publisher = "American Institute of Physics",

number = "18",

}

TY - JOUR

T1 - Characterization and orientation of adsorbed NO dimers on Ag{111} at low temperatures

AU - Brown, W. A.

AU - Gardner, P.

AU - Perez Jigato, M.

AU - King, D. A.

PY - 1995

Y1 - 1995

N2 - Reflection-absorption infrared spectroscopy (RAIRS) and near-edge x-ray absorption fine structure (NEXAFS) have been used, with isotopic 14NO/15NO mixtures, to determine the structure and orientation of the monolayer species formed by NO adsorption on Ag{111} at 40 to 60 K. The adlayer is composed of NO dimers bonded with the N-N axis in the surface plane and with the molecular plane tilted away from the surface normal by about 30°. This structure provides a simple basis for understanding the facile reaction to adsorbed N2O and O which occurs on heating to 70 to 90 K. © 1995 American Institute of Physics.

AB - Reflection-absorption infrared spectroscopy (RAIRS) and near-edge x-ray absorption fine structure (NEXAFS) have been used, with isotopic 14NO/15NO mixtures, to determine the structure and orientation of the monolayer species formed by NO adsorption on Ag{111} at 40 to 60 K. The adlayer is composed of NO dimers bonded with the N-N axis in the surface plane and with the molecular plane tilted away from the surface normal by about 30°. This structure provides a simple basis for understanding the facile reaction to adsorbed N2O and O which occurs on heating to 70 to 90 K. © 1995 American Institute of Physics.

M3 - Article

SN - 0021-9606

VL - 102

SP - 7277

EP - 7280

JO - Journal of Chemical Physics

JF - Journal of Chemical Physics

IS - 18

ER -

Characterization and orientation of adsorbed NO dimers on Ag{111} at low temperatures

Abstract

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