Charge control of the inverse trans-influence

Henry S La Pierre; Michael Rosenzweig; Boris Kosog; Christina Hauser; Frank W Heinemann; Stephen T Liddle; Karsten Meyer

doi:10.1039/C5CC07211E

Charge control of the inverse trans-influence

Henry S La Pierre, Michael Rosenzweig, Boris Kosog, Christina Hauser, Frank W Heinemann, Stephen T Liddle, Karsten Meyer

Inorganic Chemistry Group

Research output: Contribution to journal › Article › peer-review

55 Downloads (Pure)

Abstract

The synthesis and characterization of uranium(VI) mono(imido) complexes, by the oxidation of corresponding uranium(V) species, are presented. These experimental results, paired with DFT analyses, allow for the comparison of the electronic structure of uranium(VI) mono(oxo) and mono(imido) ligands within a conserved ligand framework and demonstrate that the magnitude of the ground state stabilization derived from the inverse trans-influence (ITI) is governed by the relative charge localization on the multiply bonded atom or group.

Original language	English
Pages (from-to)	16671-16674
Number of pages	3
Journal	Chemical Communications
Volume	51
Issue number	93
DOIs	https://doi.org/10.1039/C5CC07211E
Publication status	Published - 25 Sept 2015

Access to Document

10.1039/C5CC07211E

POST-PEER-REVIEW-PUBLISHERS.PDFFinal published version, 1.52 MB

Cite this

@article{1ec83d98ec1f41da8189c3afaa56c404,

title = "Charge control of the inverse trans-influence",

abstract = "The synthesis and characterization of uranium(VI) mono(imido) complexes, by the oxidation of corresponding uranium(V) species, are presented. These experimental results, paired with DFT analyses, allow for the comparison of the electronic structure of uranium(VI) mono(oxo) and mono(imido) ligands within a conserved ligand framework and demonstrate that the magnitude of the ground state stabilization derived from the inverse trans-influence (ITI) is governed by the relative charge localization on the multiply bonded atom or group.",

author = "{La Pierre}, {Henry S} and Michael Rosenzweig and Boris Kosog and Christina Hauser and Heinemann, {Frank W} and Liddle, {Stephen T} and Karsten Meyer",

year = "2015",

month = sep,

day = "25",

doi = "10.1039/C5CC07211E",

language = "English",

volume = "51",

pages = "16671--16674",

journal = "Chemical Communications",

issn = "1364-548X",

publisher = "Royal Society of Chemistry",

number = "93",

}

TY - JOUR

T1 - Charge control of the inverse trans-influence

AU - La Pierre, Henry S

AU - Rosenzweig, Michael

AU - Kosog, Boris

AU - Hauser, Christina

AU - Heinemann, Frank W

AU - Liddle, Stephen T

AU - Meyer, Karsten

PY - 2015/9/25

Y1 - 2015/9/25

N2 - The synthesis and characterization of uranium(VI) mono(imido) complexes, by the oxidation of corresponding uranium(V) species, are presented. These experimental results, paired with DFT analyses, allow for the comparison of the electronic structure of uranium(VI) mono(oxo) and mono(imido) ligands within a conserved ligand framework and demonstrate that the magnitude of the ground state stabilization derived from the inverse trans-influence (ITI) is governed by the relative charge localization on the multiply bonded atom or group.

AB - The synthesis and characterization of uranium(VI) mono(imido) complexes, by the oxidation of corresponding uranium(V) species, are presented. These experimental results, paired with DFT analyses, allow for the comparison of the electronic structure of uranium(VI) mono(oxo) and mono(imido) ligands within a conserved ligand framework and demonstrate that the magnitude of the ground state stabilization derived from the inverse trans-influence (ITI) is governed by the relative charge localization on the multiply bonded atom or group.

U2 - 10.1039/C5CC07211E

DO - 10.1039/C5CC07211E

M3 - Article

SN - 1364-548X

VL - 51

SP - 16671

EP - 16674

JO - Chemical Communications

JF - Chemical Communications

IS - 93

ER -

Charge control of the inverse trans-influence

Abstract

Access to Document

Other files and links

Fingerprint

Cite this