Chemical and structural stability of zirconium-based metal-organic frameworks with large three-dimensional pores by linker engineering

Suresh B. Kalidindi; Sanjit Nayak; Michael E. Briggs; Susanna Jansat; Alexandros P. Katsoulidis; Gary J. Miller; John E. Warren; Dmytro Antypov; Furio Corà; Ben Slater; Mark R. Prestly; Carlos Mart-Gastaldo; Matthew J. Rosseinsky

doi:10.1002/anie.201406501

Chemical and structural stability of zirconium-based metal-organic frameworks with large three-dimensional pores by linker engineering

Suresh B. Kalidindi, Sanjit Nayak, Michael E. Briggs, Susanna Jansat, Alexandros P. Katsoulidis, Gary J. Miller, John E. Warren, Dmytro Antypov, Furio Corà, Ben Slater, Mark R. Prestly, Carlos Mart-Gastaldo, Matthew J. Rosseinsky

Research output: Contribution to journal › Article › peer-review

Abstract

The synthesis of metal-organic frameworks with large three-dimensional channels that are permanently porous and chemically stable offers new opportunities in areas such as catalysis and separation. Two linkers (L1 = 4,4′,4″,4⌄-([1,1′-biphenyl]-3,3′,5,5′-tetrayltetrakis(ethyne-2,1-diyl)) tetrabenzoic acid, L2 = 4,4′,4″,4⌄-(pyrene-1,3,6,8-tetrayltetrakis(e-thyne-2,1-diyl))tetrabenzoic acid) were used that have equivalent connectivity and dimensions but quite distinct torsional flexibility. With these, a solid solution material, [Zr₆O₄(OH)₄(L1)_2.6(L2)_0.4]·(solvent)_x, was formed that has three-dimensional crystalline permanent porosity with a surface area of over 4000 m² g^-1 that persists after immersion in water. These properties are not accessible for the isostructural phases made from the separate single linkers.

Original language	English
Pages (from-to)	221-226
Number of pages	6
Journal	Angewandte Chemie - International Edition
Volume	54
Issue number	1
DOIs	https://doi.org/10.1002/anie.201406501
Publication status	Published - 2 Jan 2015
Externally published	Yes

Keywords

Mesoporous materials
Metal-organic frameworks
Water stability
Zirconium

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10.1002/anie.201406501

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Kalidindi, S. B., Nayak, S., Briggs, M. E., Jansat, S., Katsoulidis, A. P., Miller, G. J., Warren, J. E., Antypov, D., Corà, F., Slater, B., Prestly, M. R., Mart-Gastaldo, C., & Rosseinsky, M. J. (2015). Chemical and structural stability of zirconium-based metal-organic frameworks with large three-dimensional pores by linker engineering. Angewandte Chemie - International Edition, 54(1), 221-226. https://doi.org/10.1002/anie.201406501

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title = "Chemical and structural stability of zirconium-based metal-organic frameworks with large three-dimensional pores by linker engineering",

abstract = "The synthesis of metal-organic frameworks with large three-dimensional channels that are permanently porous and chemically stable offers new opportunities in areas such as catalysis and separation. Two linkers (L1 = 4,4′,4″,4⌄-([1,1′-biphenyl]-3,3′,5,5′-tetrayltetrakis(ethyne-2,1-diyl)) tetrabenzoic acid, L2 = 4,4′,4″,4⌄-(pyrene-1,3,6,8-tetrayltetrakis(e-thyne-2,1-diyl))tetrabenzoic acid) were used that have equivalent connectivity and dimensions but quite distinct torsional flexibility. With these, a solid solution material, [Zr6O4(OH)4(L1)2.6(L2)0.4]·(solvent)x, was formed that has three-dimensional crystalline permanent porosity with a surface area of over 4000 m2 g-1 that persists after immersion in water. These properties are not accessible for the isostructural phases made from the separate single linkers.",

keywords = "Mesoporous materials, Metal-organic frameworks, Water stability, Zirconium",

author = "Kalidindi, {Suresh B.} and Sanjit Nayak and Briggs, {Michael E.} and Susanna Jansat and Katsoulidis, {Alexandros P.} and Miller, {Gary J.} and Warren, {John E.} and Dmytro Antypov and Furio Cor{\`a} and Ben Slater and Prestly, {Mark R.} and Carlos Mart-Gastaldo and Rosseinsky, {Matthew J.}",

year = "2015",

month = jan,

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doi = "10.1002/anie.201406501",

language = "English",

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Kalidindi, SB, Nayak, S, Briggs, ME, Jansat, S, Katsoulidis, AP, Miller, GJ, Warren, JE, Antypov, D, Corà, F, Slater, B, Prestly, MR, Mart-Gastaldo, C & Rosseinsky, MJ 2015, 'Chemical and structural stability of zirconium-based metal-organic frameworks with large three-dimensional pores by linker engineering', Angewandte Chemie - International Edition, vol. 54, no. 1, pp. 221-226. https://doi.org/10.1002/anie.201406501

TY - JOUR

T1 - Chemical and structural stability of zirconium-based metal-organic frameworks with large three-dimensional pores by linker engineering

AU - Kalidindi, Suresh B.

AU - Nayak, Sanjit

AU - Briggs, Michael E.

AU - Jansat, Susanna

AU - Katsoulidis, Alexandros P.

AU - Miller, Gary J.

AU - Warren, John E.

AU - Antypov, Dmytro

AU - Corà, Furio

AU - Slater, Ben

AU - Prestly, Mark R.

AU - Mart-Gastaldo, Carlos

AU - Rosseinsky, Matthew J.

PY - 2015/1/2

Y1 - 2015/1/2

N2 - The synthesis of metal-organic frameworks with large three-dimensional channels that are permanently porous and chemically stable offers new opportunities in areas such as catalysis and separation. Two linkers (L1 = 4,4′,4″,4⌄-([1,1′-biphenyl]-3,3′,5,5′-tetrayltetrakis(ethyne-2,1-diyl)) tetrabenzoic acid, L2 = 4,4′,4″,4⌄-(pyrene-1,3,6,8-tetrayltetrakis(e-thyne-2,1-diyl))tetrabenzoic acid) were used that have equivalent connectivity and dimensions but quite distinct torsional flexibility. With these, a solid solution material, [Zr6O4(OH)4(L1)2.6(L2)0.4]·(solvent)x, was formed that has three-dimensional crystalline permanent porosity with a surface area of over 4000 m2 g-1 that persists after immersion in water. These properties are not accessible for the isostructural phases made from the separate single linkers.

AB - The synthesis of metal-organic frameworks with large three-dimensional channels that are permanently porous and chemically stable offers new opportunities in areas such as catalysis and separation. Two linkers (L1 = 4,4′,4″,4⌄-([1,1′-biphenyl]-3,3′,5,5′-tetrayltetrakis(ethyne-2,1-diyl)) tetrabenzoic acid, L2 = 4,4′,4″,4⌄-(pyrene-1,3,6,8-tetrayltetrakis(e-thyne-2,1-diyl))tetrabenzoic acid) were used that have equivalent connectivity and dimensions but quite distinct torsional flexibility. With these, a solid solution material, [Zr6O4(OH)4(L1)2.6(L2)0.4]·(solvent)x, was formed that has three-dimensional crystalline permanent porosity with a surface area of over 4000 m2 g-1 that persists after immersion in water. These properties are not accessible for the isostructural phases made from the separate single linkers.

KW - Mesoporous materials

KW - Metal-organic frameworks

KW - Water stability

KW - Zirconium

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U2 - 10.1002/anie.201406501

DO - 10.1002/anie.201406501

M3 - Article

AN - SCOPUS:84920079799

SN - 1433-7851

VL - 54

SP - 221

EP - 226

JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

IS - 1

ER -

Chemical and structural stability of zirconium-based metal-organic frameworks with large three-dimensional pores by linker engineering

Abstract

Keywords

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CCDC 1006810: Experimental Crystal Structure Determination

CCDC 1006811: Experimental Crystal Structure Determination

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Chemical and structural stability of zirconium-based metal-organic frameworks with large three-dimensional pores by linker engineering

Abstract

Keywords

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Datasets

CCDC 1006810: Experimental Crystal Structure Determination

CCDC 1006811: Experimental Crystal Structure Determination

Cite this