Chemical tuning of the magnetic relaxation in dysprosium(iii) mononuclear complexes

Luke J. Batchelor; Irene Cimatti; Régis Guillot; Floriana Tuna; Wolfgang Wernsdorfer; Liviu Ungur; Liviu F. Chibotaru; Victoria E. Campbell; Talal Mallah

doi:10.1039/c4dt00846d

Chemical tuning of the magnetic relaxation in dysprosium(iii) mononuclear complexes

Luke J. Batchelor, Irene Cimatti, Régis Guillot, Floriana Tuna, Wolfgang Wernsdorfer, Liviu Ungur, Liviu F. Chibotaru, Victoria E. Campbell, Talal Mallah

Research output: Contribution to journal › Article › peer-review

Abstract

A dysprosium(iii) complex, exhibiting slow relaxation of magnetization, was prepared. Crystallographic studies showed a perturbation of local symmetry upon deprotonation of the ligand, with concomitant faster relaxation of magnetization. This was attributed to a large shift in the direction of the main magnetic axis, as indicated by ab initio calculations. © 2014 the Partner Organisations.

Original language	English
Pages (from-to)	12146-12149
Number of pages	3
Journal	Dalton Transactions
Volume	43
Issue number	32
DOIs	https://doi.org/10.1039/c4dt00846d
Publication status	Published - 28 Aug 2014

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CCDC 870723: Experimental Crystal Structure Determination
Batchelor, L. (Contributor), Cimatti, I. (Contributor), Guillot, R. (Contributor), Tuna, F. (Contributor), Wernsdorfer, W. (Contributor), Ungur, L. (Contributor), Chibotaru, L. F. (Contributor), Campbell, V. E. (Contributor) & Mallah, T. (Contributor), Cambridge Crystallographic Data Centre, 1 Jan 2014
DOI: 10.5517/ccy71v1, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/ccy71v1&sid=DataCite
Dataset
CCDC 870724: Experimental Crystal Structure Determination
Batchelor, L. (Contributor), Cimatti, I. (Contributor), Guillot, R. (Contributor), Tuna, F. (Contributor), Wernsdorfer, W. (Contributor), Ungur, L. (Contributor), Chibotaru, L. F. (Contributor), Campbell, V. E. (Contributor) & Mallah, T. (Contributor), Cambridge Crystallographic Data Centre, 1 Jan 2014
DOI: 10.5517/ccy71w2, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/ccy71w2&sid=DataCite
Dataset

Cite this

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title = "Chemical tuning of the magnetic relaxation in dysprosium(iii) mononuclear complexes",

abstract = "A dysprosium(iii) complex, exhibiting slow relaxation of magnetization, was prepared. Crystallographic studies showed a perturbation of local symmetry upon deprotonation of the ligand, with concomitant faster relaxation of magnetization. This was attributed to a large shift in the direction of the main magnetic axis, as indicated by ab initio calculations. {\textcopyright} 2014 the Partner Organisations.",

author = "Batchelor, {Luke J.} and Irene Cimatti and R{\'e}gis Guillot and Floriana Tuna and Wolfgang Wernsdorfer and Liviu Ungur and Chibotaru, {Liviu F.} and Campbell, {Victoria E.} and Talal Mallah",

year = "2014",

month = aug,

day = "28",

doi = "10.1039/c4dt00846d",

language = "English",

volume = "43",

pages = "12146--12149",

journal = "Dalton Transactions",

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TY - JOUR

T1 - Chemical tuning of the magnetic relaxation in dysprosium(iii) mononuclear complexes

AU - Batchelor, Luke J.

AU - Cimatti, Irene

AU - Guillot, Régis

AU - Tuna, Floriana

AU - Wernsdorfer, Wolfgang

AU - Ungur, Liviu

AU - Chibotaru, Liviu F.

AU - Campbell, Victoria E.

AU - Mallah, Talal

PY - 2014/8/28

Y1 - 2014/8/28

N2 - A dysprosium(iii) complex, exhibiting slow relaxation of magnetization, was prepared. Crystallographic studies showed a perturbation of local symmetry upon deprotonation of the ligand, with concomitant faster relaxation of magnetization. This was attributed to a large shift in the direction of the main magnetic axis, as indicated by ab initio calculations. © 2014 the Partner Organisations.

AB - A dysprosium(iii) complex, exhibiting slow relaxation of magnetization, was prepared. Crystallographic studies showed a perturbation of local symmetry upon deprotonation of the ligand, with concomitant faster relaxation of magnetization. This was attributed to a large shift in the direction of the main magnetic axis, as indicated by ab initio calculations. © 2014 the Partner Organisations.

U2 - 10.1039/c4dt00846d

DO - 10.1039/c4dt00846d

M3 - Article

SN - 1477-9234

VL - 43

SP - 12146

EP - 12149

JO - Dalton Transactions

JF - Dalton Transactions

IS - 32

ER -

Chemical tuning of the magnetic relaxation in dysprosium(iii) mononuclear complexes

Abstract

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Datasets

CCDC 870723: Experimental Crystal Structure Determination

CCDC 870724: Experimental Crystal Structure Determination

Cite this