Chlorine-Enabled Electron Doping in Solution-Synthesized SnSe Thermoelectric Nanomaterials

Guang Han; Srinivas  Popuri; Heather Greer; Lourdes  Llin; Jan-Willem Bos; Wuzong  Zhou; Douglas Paul; Hervé  Ménard; Andrew Knox; Andrea  Montecucco; Jonathan  Siviter; Elena  Man; Wen-guang Li; Manosh  Paul; Min  Gao; Tracy Sweet; Robert Freer; Feridoon Azough; Hasan  Baig; Tapas  Mallick; Duncan Gregory

doi:10.1002/aenm.201602328

Chlorine-Enabled Electron Doping in Solution-Synthesized SnSe Thermoelectric Nanomaterials

Guang Han, Srinivas Popuri, Heather Greer, Lourdes Llin, Jan-Willem Bos, Wuzong Zhou, Douglas Paul, Hervé Ménard, Andrew Knox, Andrea Montecucco, Jonathan Siviter, Elena Man, Wen-guang Li, Manosh Paul, Min Gao, Tracy Sweet, Robert Freer, Feridoon Azough, Hasan Baig, Tapas MallickDuncan Gregory

Research output: Contribution to journal › Article › peer-review

Abstract

An aqueous solution method is developed for the facile synthesis of Cl-containing SnSe nanoparticles in 10 g quantities per batch. The particle size and Cl concentration of the nanoparticles can be efficiently tuned as a function of reaction duration. Hot pressing produces n-type Cl-doped SnSe nanostructured compacts with thermoelectric power factors optimized via control of Cl dopant concentration. This approach, combining an energy-efficient solution synthesis with hot pressing, provides a simple, rapid, and low-cost route to high performance n-type SnSe thermoelectric materials.

Original language	English
Article number	1602328
Journal	Advanced Energy Materials
Early online date	20 Feb 2017
DOIs	https://doi.org/10.1002/aenm.201602328
Publication status	Published - 5 Jul 2017

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Han, G., Popuri, S., Greer, H., Llin, L., Bos, J-W., Zhou, W., Paul, D., Ménard, H., Knox, A., Montecucco, A., Siviter, J., Man, E., Li, W., Paul, M., Gao, M., Sweet, T., Freer, R., Azough, F., Baig, H., ... Gregory, D. (2017). Chlorine-Enabled Electron Doping in Solution-Synthesized SnSe Thermoelectric Nanomaterials. Advanced Energy Materials, Article 1602328. Advance online publication. https://doi.org/10.1002/aenm.201602328

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title = "Chlorine-Enabled Electron Doping in Solution-Synthesized SnSe Thermoelectric Nanomaterials",

abstract = "An aqueous solution method is developed for the facile synthesis of Cl-containing SnSe nanoparticles in 10 g quantities per batch. The particle size and Cl concentration of the nanoparticles can be efficiently tuned as a function of reaction duration. Hot pressing produces n-type Cl-doped SnSe nanostructured compacts with thermoelectric power factors optimized via control of Cl dopant concentration. This approach, combining an energy-efficient solution synthesis with hot pressing, provides a simple, rapid, and low-cost route to high performance n-type SnSe thermoelectric materials.",

author = "Guang Han and Srinivas Popuri and Heather Greer and Lourdes Llin and Jan-Willem Bos and Wuzong Zhou and Douglas Paul and Herv{\'e} M{\'e}nard and Andrew Knox and Andrea Montecucco and Jonathan Siviter and Elena Man and Wen-guang Li and Manosh Paul and Min Gao and Tracy Sweet and Robert Freer and Feridoon Azough and Hasan Baig and Tapas Mallick and Duncan Gregory",

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doi = "10.1002/aenm.201602328",

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Han, G, Popuri, S, Greer, H, Llin, L, Bos, J-W, Zhou, W, Paul, D, Ménard, H, Knox, A, Montecucco, A, Siviter, J, Man, E, Li, W, Paul, M, Gao, M, Sweet, T, Freer, R, Azough, F, Baig, H, Mallick, T & Gregory, D 2017, 'Chlorine-Enabled Electron Doping in Solution-Synthesized SnSe Thermoelectric Nanomaterials', Advanced Energy Materials. https://doi.org/10.1002/aenm.201602328

TY - JOUR

T1 - Chlorine-Enabled Electron Doping in Solution-Synthesized SnSe Thermoelectric Nanomaterials

AU - Han, Guang

AU - Popuri, Srinivas

AU - Greer, Heather

AU - Llin, Lourdes

AU - Bos, Jan-Willem

AU - Zhou, Wuzong

AU - Paul, Douglas

AU - Ménard, Hervé

AU - Knox, Andrew

AU - Montecucco, Andrea

AU - Siviter, Jonathan

AU - Man, Elena

AU - Li, Wen-guang

AU - Paul, Manosh

AU - Gao, Min

AU - Sweet, Tracy

AU - Freer, Robert

AU - Azough, Feridoon

AU - Baig, Hasan

AU - Mallick, Tapas

AU - Gregory, Duncan

PY - 2017/7/5

Y1 - 2017/7/5

N2 - An aqueous solution method is developed for the facile synthesis of Cl-containing SnSe nanoparticles in 10 g quantities per batch. The particle size and Cl concentration of the nanoparticles can be efficiently tuned as a function of reaction duration. Hot pressing produces n-type Cl-doped SnSe nanostructured compacts with thermoelectric power factors optimized via control of Cl dopant concentration. This approach, combining an energy-efficient solution synthesis with hot pressing, provides a simple, rapid, and low-cost route to high performance n-type SnSe thermoelectric materials.

AB - An aqueous solution method is developed for the facile synthesis of Cl-containing SnSe nanoparticles in 10 g quantities per batch. The particle size and Cl concentration of the nanoparticles can be efficiently tuned as a function of reaction duration. Hot pressing produces n-type Cl-doped SnSe nanostructured compacts with thermoelectric power factors optimized via control of Cl dopant concentration. This approach, combining an energy-efficient solution synthesis with hot pressing, provides a simple, rapid, and low-cost route to high performance n-type SnSe thermoelectric materials.

U2 - 10.1002/aenm.201602328

DO - 10.1002/aenm.201602328

M3 - Article

SN - 1614-6832

JO - Advanced Energy Materials

JF - Advanced Energy Materials

M1 - 1602328

ER -

Chlorine-Enabled Electron Doping in Solution-Synthesized SnSe Thermoelectric Nanomaterials

Abstract

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