Co-Gd phosphonate complexes as magnetic refrigerants

Yan Zhen Zheng, Marco Evangelisti, Richard E P Winpenny

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    Abstract

    Three 3d-4f phosphonate complexes, [CoII 8GdIII 8(μ3-OH)4(NO3)4(O3PtBu)8(O2CtBu)16], [CoII 8GdIII 4(O3PtBu)6(O2CtBu)16] and [CoII 4GdIII 6(O3PCH2Ph)6(O2CtBu)14(MeCN)2], have been synthesized and have structures that can be related to molecular grids. Magnetic studies show they have promise as low temperature magnetic refrigerants. © The Royal Society of Chemistry 2011.
    Original languageEnglish
    Pages (from-to)99-102
    Number of pages3
    JournalChemical Science
    Volume2
    Issue number1
    DOIs
    Publication statusPublished - 2011

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