Co-Gd phosphonate complexes as magnetic refrigerants

Yan Zhen Zheng; Marco Evangelisti; Richard E P Winpenny

doi:10.1039/c0sc00371a

Co-Gd phosphonate complexes as magnetic refrigerants

Yan Zhen Zheng
, Marco Evangelisti
, Richard E P Winpenny

Research output: Contribution to journal › Article › peer-review

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Abstract

Three 3d-4f phosphonate complexes, [CoII 8GdIII 8(μ3-OH)4(NO3)4(O3PtBu)8(O2CtBu)16], [CoII 8GdIII 4(O3PtBu)6(O2CtBu)16] and [CoII 4GdIII 6(O3PCH2Ph)6(O2CtBu)14(MeCN)2], have been synthesized and have structures that can be related to molecular grids. Magnetic studies show they have promise as low temperature magnetic refrigerants. © The Royal Society of Chemistry 2011.

Original language	English
Pages (from-to)	99-102
Number of pages	3
Journal	Chemical Science
Volume	2
Issue number	1
DOIs	https://doi.org/10.1039/c0sc00371a
Publication status	Published - 2011

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CCDC 784309: Experimental Crystal Structure Determination
Zheng, Y. Z. (Contributor), Evangelisti, M. (Contributor) & Winpenny, R. (Contributor), Cambridge Crystallographic Data Centre, 2010
DOI: 10.5517/ccvb49l, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/ccvb49l&sid=DataCite
Dataset
CCDC 784310: Experimental Crystal Structure Determination
Zheng, Y. Z. (Contributor), Evangelisti, M. (Contributor) & Winpenny, R. (Contributor), Cambridge Crystallographic Data Centre, 1 Jan 2011
DOI: 10.5517/ccvb4bm, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/ccvb4bm&sid=DataCite
Dataset
CCDC 784308: Experimental Crystal Structure Determination
Zheng, Y. Z. (Contributor), Evangelisti, M. (Contributor) & Winpenny, R. (Contributor), Cambridge Crystallographic Data Centre, 2010
DOI: 10.5517/ccvb48k, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/ccvb48k&sid=DataCite
Dataset

Cite this

@article{d7099f01cd4e4fc1ab74eb33edfffeed,

title = "Co-Gd phosphonate complexes as magnetic refrigerants",

abstract = "Three 3d-4f phosphonate complexes, [CoII 8GdIII 8(μ3-OH)4(NO3)4(O3PtBu)8(O2CtBu)16], [CoII 8GdIII 4(O3PtBu)6(O2CtBu)16] and [CoII 4GdIII 6(O3PCH2Ph)6(O2CtBu)14(MeCN)2], have been synthesized and have structures that can be related to molecular grids. Magnetic studies show they have promise as low temperature magnetic refrigerants. {\textcopyright} The Royal Society of Chemistry 2011.",

author = "Zheng, \{Yan Zhen\} and Marco Evangelisti and Winpenny, \{Richard E P\}",

year = "2011",

doi = "10.1039/c0sc00371a",

language = "English",

volume = "2",

pages = "99--102",

journal = "Chemical Science",

issn = "2041-6520",

publisher = "Royal Society of Chemistry",

number = "1",

}

TY - JOUR

T1 - Co-Gd phosphonate complexes as magnetic refrigerants

AU - Zheng, Yan Zhen

AU - Evangelisti, Marco

AU - Winpenny, Richard E P

PY - 2011

Y1 - 2011

N2 - Three 3d-4f phosphonate complexes, [CoII 8GdIII 8(μ3-OH)4(NO3)4(O3PtBu)8(O2CtBu)16], [CoII 8GdIII 4(O3PtBu)6(O2CtBu)16] and [CoII 4GdIII 6(O3PCH2Ph)6(O2CtBu)14(MeCN)2], have been synthesized and have structures that can be related to molecular grids. Magnetic studies show they have promise as low temperature magnetic refrigerants. © The Royal Society of Chemistry 2011.

AB - Three 3d-4f phosphonate complexes, [CoII 8GdIII 8(μ3-OH)4(NO3)4(O3PtBu)8(O2CtBu)16], [CoII 8GdIII 4(O3PtBu)6(O2CtBu)16] and [CoII 4GdIII 6(O3PCH2Ph)6(O2CtBu)14(MeCN)2], have been synthesized and have structures that can be related to molecular grids. Magnetic studies show they have promise as low temperature magnetic refrigerants. © The Royal Society of Chemistry 2011.

U2 - 10.1039/c0sc00371a

DO - 10.1039/c0sc00371a

M3 - Article

SN - 2041-6520

VL - 2

SP - 99

EP - 102

JO - Chemical Science

JF - Chemical Science

IS - 1

ER -

Co-Gd phosphonate complexes as magnetic refrigerants

Abstract

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Datasets

CCDC 784309: Experimental Crystal Structure Determination

CCDC 784310: Experimental Crystal Structure Determination

CCDC 784308: Experimental Crystal Structure Determination

Cite this