CO2 selectivity of a 1D microporous adenine-based metal-organic framework synthesised in water

Kyriakos C. Stylianou; John E. Warren; Samantha Y. Chong; Jeremy Rabone; John Bacsa; Darren Bradshaw; Matthew J. Rosseinsky

doi:10.1039/c0cc05559j

CO2 selectivity of a 1D microporous adenine-based metal-organic framework synthesised in water

Kyriakos C. Stylianou, John E. Warren, Samantha Y. Chong, Jeremy Rabone, John Bacsa, Darren Bradshaw, Matthew J. Rosseinsky

Research output: Contribution to journal › Article › peer-review

Abstract

The coordination of adenine to Ni2+ forms a dimer unit which can be linked by 3,5-pyrazoledicarboxylic acid into chains which assemble under hydrothermal conditions via hydrogen bonding into a robust porous network. The material displays selectivity for CO2 over CH4 and an isosteric heat which increases with guest loading. © 2011 The Royal Society of Chemistry.

Original language	English
Pages (from-to)	3389-3391
Number of pages	2
Journal	Chemical Communications
Volume	47
Issue number	12
DOIs	https://doi.org/10.1039/c0cc05559j
Publication status	Published - 28 Mar 2011
Externally published	Yes

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10.1039/c0cc05559j

CCDC 804576: Experimental Crystal Structure Determination
Stylianou, K. C. (Contributor), Warren, J. (Contributor), Chong, S. Y. (Contributor), Rabone, J. (Contributor), Bacsa, J. (Contributor), Bradshaw, D. (Contributor) & Rosseinsky, M. J. (Contributor), Cambridge Crystallographic Data Centre, 1 Jan 2011
DOI: 10.5517/ccw0725, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/ccw0725&sid=DataCite
Dataset

Cite this

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title = "CO2 selectivity of a 1D microporous adenine-based metal-organic framework synthesised in water",

abstract = "The coordination of adenine to Ni2+ forms a dimer unit which can be linked by 3,5-pyrazoledicarboxylic acid into chains which assemble under hydrothermal conditions via hydrogen bonding into a robust porous network. The material displays selectivity for CO2 over CH4 and an isosteric heat which increases with guest loading. {\textcopyright} 2011 The Royal Society of Chemistry.",

author = "Stylianou, {Kyriakos C.} and Warren, {John E.} and Chong, {Samantha Y.} and Jeremy Rabone and John Bacsa and Darren Bradshaw and Rosseinsky, {Matthew J.}",

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language = "English",

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T1 - CO2 selectivity of a 1D microporous adenine-based metal-organic framework synthesised in water

AU - Stylianou, Kyriakos C.

AU - Warren, John E.

AU - Chong, Samantha Y.

AU - Rabone, Jeremy

AU - Bacsa, John

AU - Bradshaw, Darren

AU - Rosseinsky, Matthew J.

N1 - 12

PY - 2011/3/28

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N2 - The coordination of adenine to Ni2+ forms a dimer unit which can be linked by 3,5-pyrazoledicarboxylic acid into chains which assemble under hydrothermal conditions via hydrogen bonding into a robust porous network. The material displays selectivity for CO2 over CH4 and an isosteric heat which increases with guest loading. © 2011 The Royal Society of Chemistry.

AB - The coordination of adenine to Ni2+ forms a dimer unit which can be linked by 3,5-pyrazoledicarboxylic acid into chains which assemble under hydrothermal conditions via hydrogen bonding into a robust porous network. The material displays selectivity for CO2 over CH4 and an isosteric heat which increases with guest loading. © 2011 The Royal Society of Chemistry.

U2 - 10.1039/c0cc05559j

DO - 10.1039/c0cc05559j

M3 - Article

SN - 1359-7345

VL - 47

SP - 3389

EP - 3391

JO - Chemical Communications

JF - Chemical Communications

IS - 12

ER -

CO2 selectivity of a 1D microporous adenine-based metal-organic framework synthesised in water

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CCDC 804576: Experimental Crystal Structure Determination

Cite this