Comment on the preparation of the ionic liquid 1-ethyl-3-methylimidazolium ethanoate: A unique monomeric, homoleptic pentacoordinate lead ethanoate complex

J. T. Hamill; C. Hardacre; M. Nieuwenhuyzen; K. R. Seddon; S. A. Thompson; B. Ellis

Comment on the preparation of the ionic liquid 1-ethyl-3-methylimidazolium ethanoate: A unique monomeric, homoleptic pentacoordinate lead ethanoate complex

J. T. Hamill, C. Hardacre, M. Nieuwenhuyzen^*, K. R. Seddon, S. A. Thompson, B. Ellis

^*Corresponding author for this work

Queen's University Belfast

Research output: Contribution to journal › Article › peer-review

Abstract

Atomic absorption spectroscopy of the ionic liquid 1-ethyl- 3-methylimidazolium ethanoate ([emim]₂[O₂CMe]), prepared according to International Patent WO 96/18459, showed it to contain large amounts of lead impurity: (ca. 0.5 M): [emim]₂[Pb(O₂CMe)₄] was isolated and shown crystallographically to contain the first known example of a monomeric, homoleptic pentacoordinate lead(II) carboxylate complex, with a stereochemically active lone-pair.

Original language	English
Pages (from-to)	1929-1930
Number of pages	2
Journal	Chemical Communications
Issue number	19
Publication status	Published - 7 Oct 2000

Cite this

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title = "Comment on the preparation of the ionic liquid 1-ethyl-3-methylimidazolium ethanoate: A unique monomeric, homoleptic pentacoordinate lead ethanoate complex",

abstract = "Atomic absorption spectroscopy of the ionic liquid 1-ethyl- 3-methylimidazolium ethanoate ([emim]2[O2CMe]), prepared according to International Patent WO 96/18459, showed it to contain large amounts of lead impurity: (ca. 0.5 M): [emim]2[Pb(O2CMe)4] was isolated and shown crystallographically to contain the first known example of a monomeric, homoleptic pentacoordinate lead(II) carboxylate complex, with a stereochemically active lone-pair.",

author = "Hamill, {J. T.} and C. Hardacre and M. Nieuwenhuyzen and Seddon, {K. R.} and Thompson, {S. A.} and B. Ellis",

year = "2000",

month = oct,

day = "7",

language = "English",

pages = "1929--1930",

journal = "Chemical Communications",

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T1 - Comment on the preparation of the ionic liquid 1-ethyl-3-methylimidazolium ethanoate

T2 - A unique monomeric, homoleptic pentacoordinate lead ethanoate complex

AU - Hamill, J. T.

AU - Hardacre, C.

AU - Nieuwenhuyzen, M.

AU - Seddon, K. R.

AU - Thompson, S. A.

AU - Ellis, B.

PY - 2000/10/7

Y1 - 2000/10/7

N2 - Atomic absorption spectroscopy of the ionic liquid 1-ethyl- 3-methylimidazolium ethanoate ([emim]2[O2CMe]), prepared according to International Patent WO 96/18459, showed it to contain large amounts of lead impurity: (ca. 0.5 M): [emim]2[Pb(O2CMe)4] was isolated and shown crystallographically to contain the first known example of a monomeric, homoleptic pentacoordinate lead(II) carboxylate complex, with a stereochemically active lone-pair.

AB - Atomic absorption spectroscopy of the ionic liquid 1-ethyl- 3-methylimidazolium ethanoate ([emim]2[O2CMe]), prepared according to International Patent WO 96/18459, showed it to contain large amounts of lead impurity: (ca. 0.5 M): [emim]2[Pb(O2CMe)4] was isolated and shown crystallographically to contain the first known example of a monomeric, homoleptic pentacoordinate lead(II) carboxylate complex, with a stereochemically active lone-pair.

UR - http://www.scopus.com/inward/record.url?scp=0034619247&partnerID=8YFLogxK

M3 - Article

AN - SCOPUS:0034619247

SN - 1359-7345

SP - 1929

EP - 1930

JO - Chemical Communications

JF - Chemical Communications

IS - 19

ER -

Comment on the preparation of the ionic liquid 1-ethyl-3-methylimidazolium ethanoate: A unique monomeric, homoleptic pentacoordinate lead ethanoate complex

Abstract

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