Control of porosity geometry in amino acid derived nanoporous materials

J P Barrio; J N Rebilly; B Carter; D Bradshaw; J Bacsa; A Y Ganin; H Park; A Trewin; R Vaidhyanathan; A I Cooper; J E Warren; M J Rosseinsky

doi:10.1002/chem.200701556

Control of porosity geometry in amino acid derived nanoporous materials

J P Barrio, J N Rebilly, B Carter, D Bradshaw, J Bacsa, A Y Ganin, H Park, A Trewin, R Vaidhyanathan, A I Cooper, J E Warren, M J Rosseinsky

Research output: Contribution to journal › Article › peer-review

Abstract

Substitution of the pillaring ligand in the homochiral open-framework [Ni-2(L-asp)(2)(bipy)] by extended bipy-type ligands leads to a family of layer-structured, homochiral metal-organic frameworks. The {1D} channel topology can be modified by the nature of the organic linker, with shape, cross-section and the chemical functionality tuneable. In addition, the volume of these channels can be increased by up to 36\% compared to the parent [Ni-2(L-asp)(2)(bipy)]. The linker 1,4-dipyridylbenzene (3rbp) gives access to a new layered homochiral framework [Ni-2(L-asp)(2)(3rbp)] with channels of a different shape. In specific cases, non-porous analogues with the linker also present as a guest can be activated to give porous materials after sublimation. Their {CO2} uptake shows an increase of up to 30\% with respect to the parent [Ni,(L-asp)(2)(bipy)] framework.

Original language	English
Pages (from-to)	4521-4532
Number of pages	12
Journal	Chemistry-A European Journal
Volume	14
DOIs	https://doi.org/10.1002/chem.200701556
Publication status	Published - 2008

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10.1002/chem.200701556

CCDC 662393: Experimental Crystal Structure Determination
Barrio, J. P. (Contributor), Rebilly, J. N. (Contributor), Carter, B. (Contributor), Bradshaw, D. (Contributor), Bacsa, J. (Contributor), Ganin, A. Y. (Contributor), Park, H. (Contributor), Trewin, A. (Contributor), Vaidhyanathan, R. (Contributor), Cooper, A. I. (Contributor), Warren, J. (Contributor) & Rosseinsky, M. J. (Contributor), Cambridge Crystallographic Data Centre, 1 Jan 2008
DOI: 10.5517/ccq78jq, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/ccq78jq&sid=DataCite
Dataset
CCDC 662394: Experimental Crystal Structure Determination
Barrio, J. P. (Contributor), Rebilly, J. N. (Contributor), Carter, B. (Contributor), Bradshaw, D. (Contributor), Bacsa, J. (Contributor), Ganin, A. Y. (Contributor), Park, H. (Contributor), Trewin, A. (Contributor), Vaidhyanathan, R. (Contributor), Cooper, A. I. (Contributor), Warren, J. (Contributor) & Rosseinsky, M. J. (Contributor), Cambridge Crystallographic Data Centre, 1 Jan 2008
DOI: 10.5517/ccq78kr, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/ccq78kr&sid=DataCite
Dataset
CCDC 662396: Experimental Crystal Structure Determination
Barrio, J. P. (Contributor), Rebilly, J. N. (Contributor), Carter, B. (Contributor), Bradshaw, D. (Contributor), Bacsa, J. (Contributor), Ganin, A. Y. (Contributor), Park, H. (Contributor), Trewin, A. (Contributor), Vaidhyanathan, R. (Contributor), Cooper, A. I. (Contributor), Warren, J. (Contributor) & Rosseinsky, M. J. (Contributor), Cambridge Crystallographic Data Centre, 1 Jan 2008
DOI: 10.5517/ccq78mt, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/ccq78mt&sid=DataCite
Dataset

Cite this

@article{3219991711564c139a0af2e9b59c3bd3,

title = "Control of porosity geometry in amino acid derived nanoporous materials",

abstract = "Substitution of the pillaring ligand in the homochiral open-framework [Ni-2(L-asp)(2)(bipy)] by extended bipy-type ligands leads to a family of layer-structured, homochiral metal-organic frameworks. The {1D} channel topology can be modified by the nature of the organic linker, with shape, cross-section and the chemical functionality tuneable. In addition, the volume of these channels can be increased by up to 36\% compared to the parent [Ni-2(L-asp)(2)(bipy)]. The linker 1,4-dipyridylbenzene (3rbp) gives access to a new layered homochiral framework [Ni-2(L-asp)(2)(3rbp)] with channels of a different shape. In specific cases, non-porous analogues with the linker also present as a guest can be activated to give porous materials after sublimation. Their {CO2} uptake shows an increase of up to 30\% with respect to the parent [Ni,(L-asp)(2)(bipy)] framework.",

author = "Barrio, {J P} and Rebilly, {J N} and B Carter and D Bradshaw and J Bacsa and Ganin, {A Y} and H Park and A Trewin and R Vaidhyanathan and Cooper, {A I} and Warren, {J E} and Rosseinsky, {M J}",

note = "15",

year = "2008",

doi = "10.1002/chem.200701556",

language = "English",

volume = "14",

pages = "4521--4532",

journal = "Chemistry-A European Journal",

issn = "0947-6539",

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TY - JOUR

T1 - Control of porosity geometry in amino acid derived nanoporous materials

AU - Barrio, J P

AU - Rebilly, J N

AU - Carter, B

AU - Bradshaw, D

AU - Bacsa, J

AU - Ganin, A Y

AU - Park, H

AU - Trewin, A

AU - Vaidhyanathan, R

AU - Cooper, A I

AU - Warren, J E

AU - Rosseinsky, M J

N1 - 15

PY - 2008

Y1 - 2008

N2 - Substitution of the pillaring ligand in the homochiral open-framework [Ni-2(L-asp)(2)(bipy)] by extended bipy-type ligands leads to a family of layer-structured, homochiral metal-organic frameworks. The {1D} channel topology can be modified by the nature of the organic linker, with shape, cross-section and the chemical functionality tuneable. In addition, the volume of these channels can be increased by up to 36\% compared to the parent [Ni-2(L-asp)(2)(bipy)]. The linker 1,4-dipyridylbenzene (3rbp) gives access to a new layered homochiral framework [Ni-2(L-asp)(2)(3rbp)] with channels of a different shape. In specific cases, non-porous analogues with the linker also present as a guest can be activated to give porous materials after sublimation. Their {CO2} uptake shows an increase of up to 30\% with respect to the parent [Ni,(L-asp)(2)(bipy)] framework.

AB - Substitution of the pillaring ligand in the homochiral open-framework [Ni-2(L-asp)(2)(bipy)] by extended bipy-type ligands leads to a family of layer-structured, homochiral metal-organic frameworks. The {1D} channel topology can be modified by the nature of the organic linker, with shape, cross-section and the chemical functionality tuneable. In addition, the volume of these channels can be increased by up to 36\% compared to the parent [Ni-2(L-asp)(2)(bipy)]. The linker 1,4-dipyridylbenzene (3rbp) gives access to a new layered homochiral framework [Ni-2(L-asp)(2)(3rbp)] with channels of a different shape. In specific cases, non-porous analogues with the linker also present as a guest can be activated to give porous materials after sublimation. Their {CO2} uptake shows an increase of up to 30\% with respect to the parent [Ni,(L-asp)(2)(bipy)] framework.

U2 - 10.1002/chem.200701556

DO - 10.1002/chem.200701556

M3 - Article

SN - 0947-6539

VL - 14

SP - 4521

EP - 4532

JO - Chemistry-A European Journal

JF - Chemistry-A European Journal

ER -

Control of porosity geometry in amino acid derived nanoporous materials

Abstract

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Datasets

CCDC 662393: Experimental Crystal Structure Determination

CCDC 662394: Experimental Crystal Structure Determination

CCDC 662396: Experimental Crystal Structure Determination

Cite this