Controlled chemistry of moisture sensitive reagents in ionic liquids

E. J. Amigues; C. Hardacre; G. Keane; M. E. Migaud; S. E. Norman; W. R. Pitner

doi:10.1149/1.3484762

Controlled chemistry of moisture sensitive reagents in ionic liquids

E. J. Amigues
, C. Hardacre
, G. Keane
, M. E. Migaud
, S. E. Norman
, W. R. Pitner

Queen's University Belfast
Merck Life Science KGaA

Research output: Chapter in Book/Conference proceeding › Conference contribution › peer-review

Abstract

Many reactions involving phosphorus reagents require highly anhydrous and inert conditions for their successful implementation. In particular, the use of PCl₃ and its derivatives for synthesis is often hampered by the inherent sensitivity of the materials themselves. Ionic liquids are emerging as green alternative solvents for a range of processes, and in particular have proven to be excellent media for highly sensitive phosphorus reagents without the need for anhydrous or inert conditions. Herein, we report the use of ionic liquids as both storage and reaction media which allows difficult and sensitive chemistry to be achieved in a more accessible manner.

Original language	English
Title of host publication	ECS Transactions
Pages	63-72
Number of pages	10
Volume	33
Edition	7
DOIs	https://doi.org/10.1149/1.3484762
Publication status	Published - 2010
Event	17th International Symposium on Molten Salts and Ionic Liquids - 218th ECS Meeting - Las Vegas, NV, United States Duration: 10 Oct 2010 → 15 Oct 2010

Conference

Conference	17th International Symposium on Molten Salts and Ionic Liquids - 218th ECS Meeting
Country/Territory	United States
City	Las Vegas, NV
Period	10/10/10 → 15/10/10

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10.1149/1.3484762

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title = "Controlled chemistry of moisture sensitive reagents in ionic liquids",

abstract = "Many reactions involving phosphorus reagents require highly anhydrous and inert conditions for their successful implementation. In particular, the use of PCl3 and its derivatives for synthesis is often hampered by the inherent sensitivity of the materials themselves. Ionic liquids are emerging as green alternative solvents for a range of processes, and in particular have proven to be excellent media for highly sensitive phosphorus reagents without the need for anhydrous or inert conditions. Herein, we report the use of ionic liquids as both storage and reaction media which allows difficult and sensitive chemistry to be achieved in a more accessible manner.",

author = "Amigues, \{E. J.\} and C. Hardacre and G. Keane and Migaud, \{M. E.\} and Norman, \{S. E.\} and Pitner, \{W. R.\}",

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T1 - Controlled chemistry of moisture sensitive reagents in ionic liquids

AU - Amigues, E. J.

AU - Hardacre, C.

AU - Keane, G.

AU - Migaud, M. E.

AU - Norman, S. E.

AU - Pitner, W. R.

PY - 2010

Y1 - 2010

N2 - Many reactions involving phosphorus reagents require highly anhydrous and inert conditions for their successful implementation. In particular, the use of PCl3 and its derivatives for synthesis is often hampered by the inherent sensitivity of the materials themselves. Ionic liquids are emerging as green alternative solvents for a range of processes, and in particular have proven to be excellent media for highly sensitive phosphorus reagents without the need for anhydrous or inert conditions. Herein, we report the use of ionic liquids as both storage and reaction media which allows difficult and sensitive chemistry to be achieved in a more accessible manner.

AB - Many reactions involving phosphorus reagents require highly anhydrous and inert conditions for their successful implementation. In particular, the use of PCl3 and its derivatives for synthesis is often hampered by the inherent sensitivity of the materials themselves. Ionic liquids are emerging as green alternative solvents for a range of processes, and in particular have proven to be excellent media for highly sensitive phosphorus reagents without the need for anhydrous or inert conditions. Herein, we report the use of ionic liquids as both storage and reaction media which allows difficult and sensitive chemistry to be achieved in a more accessible manner.

UR - https://www.scopus.com/pages/publications/79952681674

U2 - 10.1149/1.3484762

DO - 10.1149/1.3484762

M3 - Conference contribution

AN - SCOPUS:79952681674

SN - 9781566778268

VL - 33

SP - 63

EP - 72

BT - ECS Transactions

T2 - 17th International Symposium on Molten Salts and Ionic Liquids - 218th ECS Meeting

Y2 - 10 October 2010 through 15 October 2010

ER -

Controlled chemistry of moisture sensitive reagents in ionic liquids

Abstract

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