Controlled Synthesis of Nanoscopic Metal Cages

Jesus Ferrando Soria; Antonio Fernandez; Eufemio Moreno Pineda; Sarah Varey; Ralph Adams; Inigo Vitorica-Yrezabal; Floriana Tuna; Grigore Timco; Christopher Muryn; Richard Winpenny

doi:10.1021/jacs.5b04664

Controlled Synthesis of Nanoscopic Metal Cages

Jesus Ferrando Soria, Antonio Fernandez, Eufemio Moreno Pineda, Sarah Varey, Ralph Adams, Inigo Vitorica-Yrezabal, Floriana Tuna, Grigore Timco, Christopher Muryn, Richard Winpenny

Research output: Contribution to journal › Article › peer-review

Abstract

Here we show an elegant and general route to the assembly of a giant {M12C24} cage from 12 palladium ions (M) and 24 heterometallic octanuclear coordination cages (C = {Cr7Ni-Py2}). The molecule is 8 nm in size, and the methods for its synthesis and characterization provide a basis for future developments at this scale.

Original language	English
Pages (from-to)	7644–7647
Number of pages	4
Journal	Journal of the American Chemical Society
Volume	137
Issue number	24
DOIs	https://doi.org/10.1021/jacs.5b04664
Publication status	Published - 5 Jun 2015

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10.1021/jacs.5b04664Licence: CC BY

CCDC 1052349: Experimental Crystal Structure Determination
Ferrando-Soria, J. (Contributor), Fernandez, A. (Contributor), Moreno Pineda, E. (Contributor), Varey, S. (Contributor), Adams, R. (Contributor), Vitorica-Yrezabal, I. (Contributor), Tuna, F. (Contributor), Timco, G. (Contributor), Muryn, C. (Contributor) & Winpenny, R. (Contributor), Cambridge Crystallographic Data Centre, 1 Jan 2015
DOI: 10.5517/cc14b1r8, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/cc14b1r8&sid=DataCite
Dataset
CCDC 1052350: Experimental Crystal Structure Determination
Ferrando-Soria, J. (Contributor), Fernandez, A. (Contributor), Moreno Pineda, E. (Contributor), Varey, S. (Contributor), Adams, R. (Contributor), Vitorica-Yrezabal, I. (Contributor), Tuna, F. (Contributor), Timco, G. (Contributor), Muryn, C. (Contributor) & Winpenny, R. (Contributor), Cambridge Crystallographic Data Centre, 1 Jan 2015
DOI: 10.5517/cc14b1s9, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/cc14b1s9&sid=DataCite
Dataset
CCDC 1052348: Experimental Crystal Structure Determination
Ferrando-Soria, J. (Contributor), Fernandez, A. (Contributor), Moreno Pineda, E. (Contributor), Varey, S. (Contributor), Adams, R. (Contributor), Vitorica-Yrezabal, I. (Contributor), Tuna, F. (Contributor), Timco, G. (Contributor), Muryn, C. (Contributor) & Winpenny, R. (Contributor), Cambridge Crystallographic Data Centre, 1 Jan 2015
DOI: 10.5517/cc14b1q7, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/cc14b1q7&sid=DataCite
Dataset

Cite this

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title = "Controlled Synthesis of Nanoscopic Metal Cages",

abstract = "Here we show an elegant and general route to the assembly of a giant {M12C24} cage from 12 palladium ions (M) and 24 heterometallic octanuclear coordination cages (C = {Cr7Ni-Py2}). The molecule is 8 nm in size, and the methods for its synthesis and characterization provide a basis for future developments at this scale.",

author = "{Ferrando Soria}, Jesus and Antonio Fernandez and {Moreno Pineda}, Eufemio and Sarah Varey and Ralph Adams and Inigo Vitorica-Yrezabal and Floriana Tuna and Grigore Timco and Christopher Muryn and Richard Winpenny",

note = "Ferrando-Soria, Jesus Fernandez, Antonio Moreno Pineda, Eufemio Varey, Sarah A Adams, Ralph W Vitorica-Yrezabal, Inigo J Tuna, Floriana Timco, Grigore A Muryn, Christopher A Winpenny, Richard E P eng 2015/06/06 06:00 J Am Chem Soc. 2015 Jun 24;137(24):7644-7. doi: 10.1021/jacs.5b04664. Epub 2015 Jun 10.",

year = "2015",

month = jun,

day = "5",

doi = "10.1021/jacs.5b04664",

language = "English",

volume = "137",

pages = "7644–7647",

journal = "Journal of the American Chemical Society",

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TY - JOUR

T1 - Controlled Synthesis of Nanoscopic Metal Cages

AU - Ferrando Soria, Jesus

AU - Fernandez, Antonio

AU - Moreno Pineda, Eufemio

AU - Varey, Sarah

AU - Adams, Ralph

AU - Vitorica-Yrezabal, Inigo

AU - Tuna, Floriana

AU - Timco, Grigore

AU - Muryn, Christopher

AU - Winpenny, Richard

N1 - Ferrando-Soria, Jesus Fernandez, Antonio Moreno Pineda, Eufemio Varey, Sarah A Adams, Ralph W Vitorica-Yrezabal, Inigo J Tuna, Floriana Timco, Grigore A Muryn, Christopher A Winpenny, Richard E P eng 2015/06/06 06:00 J Am Chem Soc. 2015 Jun 24;137(24):7644-7. doi: 10.1021/jacs.5b04664. Epub 2015 Jun 10.

PY - 2015/6/5

Y1 - 2015/6/5

N2 - Here we show an elegant and general route to the assembly of a giant {M12C24} cage from 12 palladium ions (M) and 24 heterometallic octanuclear coordination cages (C = {Cr7Ni-Py2}). The molecule is 8 nm in size, and the methods for its synthesis and characterization provide a basis for future developments at this scale.

AB - Here we show an elegant and general route to the assembly of a giant {M12C24} cage from 12 palladium ions (M) and 24 heterometallic octanuclear coordination cages (C = {Cr7Ni-Py2}). The molecule is 8 nm in size, and the methods for its synthesis and characterization provide a basis for future developments at this scale.

U2 - 10.1021/jacs.5b04664

DO - 10.1021/jacs.5b04664

M3 - Article

SN - 1520-5126

VL - 137

SP - 7644

EP - 7647

JO - Journal of the American Chemical Society

JF - Journal of the American Chemical Society

IS - 24

ER -

Controlled Synthesis of Nanoscopic Metal Cages

Abstract

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Datasets

CCDC 1052349: Experimental Crystal Structure Determination

CCDC 1052350: Experimental Crystal Structure Determination

CCDC 1052348: Experimental Crystal Structure Determination

Cite this