Controlling chlorination versus cyclosulfonation of cis-diols using ionic liquid solvents

Christopher Hardacre; Marie E. Migaud; Kerry Anne Ness

doi:10.1039/c2nj40180k

Controlling chlorination versus cyclosulfonation of cis-diols using ionic liquid solvents

Christopher Hardacre^*, Marie E. Migaud, Kerry Anne Ness

^*Corresponding author for this work

Queen's University Belfast

Research output: Contribution to journal › Article › peer-review

Abstract

Diol reactivity can be manipulated in ionic liquids to selectively give chlorinated or cyclic sulfite/sulfate products depending on the ionic liquid used and the presence or absence of base. In comparison with reactions in dichloromethane, the ionic liquid mediated reactions show greatly improved yields and product stability.

Original language	English
Pages (from-to)	2316-2321
Number of pages	6
Journal	New Journal of Chemistry
Volume	36
Issue number	11
DOIs	https://doi.org/10.1039/c2nj40180k
Publication status	Published - 2012

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title = "Controlling chlorination versus cyclosulfonation of cis-diols using ionic liquid solvents",

abstract = "Diol reactivity can be manipulated in ionic liquids to selectively give chlorinated or cyclic sulfite/sulfate products depending on the ionic liquid used and the presence or absence of base. In comparison with reactions in dichloromethane, the ionic liquid mediated reactions show greatly improved yields and product stability.",

author = "Christopher Hardacre and Migaud, {Marie E.} and Ness, {Kerry Anne}",

year = "2012",

doi = "10.1039/c2nj40180k",

language = "English",

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AU - Hardacre, Christopher

AU - Migaud, Marie E.

AU - Ness, Kerry Anne

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N2 - Diol reactivity can be manipulated in ionic liquids to selectively give chlorinated or cyclic sulfite/sulfate products depending on the ionic liquid used and the presence or absence of base. In comparison with reactions in dichloromethane, the ionic liquid mediated reactions show greatly improved yields and product stability.

AB - Diol reactivity can be manipulated in ionic liquids to selectively give chlorinated or cyclic sulfite/sulfate products depending on the ionic liquid used and the presence or absence of base. In comparison with reactions in dichloromethane, the ionic liquid mediated reactions show greatly improved yields and product stability.

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U2 - 10.1039/c2nj40180k

DO - 10.1039/c2nj40180k

M3 - Article

AN - SCOPUS:84867521300

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SP - 2316

EP - 2321

JO - New Journal of Chemistry

JF - New Journal of Chemistry

IS - 11

ER -

Controlling chlorination versus cyclosulfonation of cis-diols using ionic liquid solvents

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