Copper-induced N-N bond cleavage results in an octanuclear expanded-core grid-like complex

Nicholas G. White; Jonathan A. Kitchen; John A. Joule; Sally Brooker

doi:10.1039/c2cc32018e

Copper-induced N-N bond cleavage results in an octanuclear expanded-core grid-like complex

Nicholas G. White, Jonathan A. Kitchen, John A. Joule, Sally Brooker^*

^*Corresponding author for this work

University of Otago

Research output: Contribution to journal › Article › peer-review

Abstract

Reaction of copper(i) acetate and 4-amino-3,5-di(2-pyridyl)-1,2,4-triazole (adpt) in methanol under ambient conditions yields octanuclear [Cu ^II ₈(dpt) ₄(OH) ₄(OAc) ₈]; OAc = acetate anion, and dpt ^- = anion of deaminated adpt, 3,5-di(2-pyridyl)-1,2,4-triazolate. However, reaction of copper(ii) acetate with dptH gives tetranuclear [Cu ^II ₄(dpt) ₂(OH)(OMe) (OAc) ₄].

Original language	English
Pages (from-to)	6229-6231
Number of pages	3
Journal	Chemical Communications
Volume	48
Issue number	50
DOIs	https://doi.org/10.1039/c2cc32018e
Publication status	Published - 25 Jun 2012

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10.1039/c2cc32018e

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@article{98e9778c044e47dd8e936ad823677b45,

title = "Copper-induced N-N bond cleavage results in an octanuclear expanded-core grid-like complex",

abstract = "Reaction of copper(i) acetate and 4-amino-3,5-di(2-pyridyl)-1,2,4-triazole (adpt) in methanol under ambient conditions yields octanuclear [Cu II 8(dpt) 4(OH) 4(OAc) 8]; OAc = acetate anion, and dpt - = anion of deaminated adpt, 3,5-di(2-pyridyl)-1,2,4-triazolate. However, reaction of copper(ii) acetate with dptH gives tetranuclear [Cu II 4(dpt) 2(OH)(OMe) (OAc) 4].",

author = "White, {Nicholas G.} and Kitchen, {Jonathan A.} and Joule, {John A.} and Sally Brooker",

year = "2012",

month = jun,

day = "25",

doi = "10.1039/c2cc32018e",

language = "English",

volume = "48",

pages = "6229--6231",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

number = "50",

}

TY - JOUR

T1 - Copper-induced N-N bond cleavage results in an octanuclear expanded-core grid-like complex

AU - White, Nicholas G.

AU - Kitchen, Jonathan A.

AU - Joule, John A.

AU - Brooker, Sally

PY - 2012/6/25

Y1 - 2012/6/25

N2 - Reaction of copper(i) acetate and 4-amino-3,5-di(2-pyridyl)-1,2,4-triazole (adpt) in methanol under ambient conditions yields octanuclear [Cu II 8(dpt) 4(OH) 4(OAc) 8]; OAc = acetate anion, and dpt - = anion of deaminated adpt, 3,5-di(2-pyridyl)-1,2,4-triazolate. However, reaction of copper(ii) acetate with dptH gives tetranuclear [Cu II 4(dpt) 2(OH)(OMe) (OAc) 4].

AB - Reaction of copper(i) acetate and 4-amino-3,5-di(2-pyridyl)-1,2,4-triazole (adpt) in methanol under ambient conditions yields octanuclear [Cu II 8(dpt) 4(OH) 4(OAc) 8]; OAc = acetate anion, and dpt - = anion of deaminated adpt, 3,5-di(2-pyridyl)-1,2,4-triazolate. However, reaction of copper(ii) acetate with dptH gives tetranuclear [Cu II 4(dpt) 2(OH)(OMe) (OAc) 4].

UR - http://www.scopus.com/inward/record.url?scp=84861651628&partnerID=8YFLogxK

U2 - 10.1039/c2cc32018e

DO - 10.1039/c2cc32018e

M3 - Article

AN - SCOPUS:84861651628

SN - 1359-7345

VL - 48

SP - 6229

EP - 6231

JO - Chemical Communications

JF - Chemical Communications

IS - 50

ER -

Copper-induced N-N bond cleavage results in an octanuclear expanded-core grid-like complex

Abstract

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CCDC 751993: Experimental Crystal Structure Determination

CCDC 751994: Experimental Crystal Structure Determination

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Copper-induced N-N bond cleavage results in an octanuclear expanded-core grid-like complex

Abstract

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Datasets

CCDC 751993: Experimental Crystal Structure Determination

CCDC 751994: Experimental Crystal Structure Determination

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