TY - JOUR
T1 - Crystal and molecular structure of a new μ-oxo-bridged iron(III) dimer formed with the nitrilotriacetate ligand
AU - Heath, Sarah L.
AU - Powell, Anne K.
AU - Utting, Helen L.
AU - Helliwell, Madeleine
PY - 1992
Y1 - 1992
N2 - The molecular structure of the oxo-bridged dimer barium μ-oxo-bis{aqua[nitrilo-κN-triacetato(3-)-κ 3O,O′,O″]ferrate(1-)}-water(1/4), Ba[{Fe(nta)(H2O)}2O]·4H2O, which has an Fe-O-Fe angle of 153.2(6)°has been determined by X-ray crystallography. The iron ions are six-co-ordinate with one tetradentate nta ligand and one water molecule completing the co-ordination sphere. The relationship of this compound to other iron-nta complexes is discussed in the context of the hydrolysis reactions of iron(III) in aqueous solutions.
AB - The molecular structure of the oxo-bridged dimer barium μ-oxo-bis{aqua[nitrilo-κN-triacetato(3-)-κ 3O,O′,O″]ferrate(1-)}-water(1/4), Ba[{Fe(nta)(H2O)}2O]·4H2O, which has an Fe-O-Fe angle of 153.2(6)°has been determined by X-ray crystallography. The iron ions are six-co-ordinate with one tetradentate nta ligand and one water molecule completing the co-ordination sphere. The relationship of this compound to other iron-nta complexes is discussed in the context of the hydrolysis reactions of iron(III) in aqueous solutions.
UR - http://www.scopus.com/inward/record.url?scp=37049080537&partnerID=8YFLogxK
U2 - 10.1039/DT9920000305
DO - 10.1039/DT9920000305
M3 - Article
AN - SCOPUS:37049080537
SN - 1472-7773
SP - 305
EP - 307
JO - Journal of the Chemical Society, Dalton Transactions
JF - Journal of the Chemical Society, Dalton Transactions
IS - 2
ER -