Crystal engineering of microporous 'Chinese-lantern' compounds to improve their ability to reversibly adsorb sulfur dioxide

W. I. Cross; S. M. Godfrey; C. A. McAuliffe; R. G. Pritchard

doi:10.1039/b101263k

Crystal engineering of microporous 'Chinese-lantern' compounds to improve their ability to reversibly adsorb sulfur dioxide

W. I. Cross, S. M. Godfrey, C. A. McAuliffe, R. G. Pritchard

Research output: Contribution to journal › Article › peer-review

Abstract

Three new 'Chinese lantern' complexes [XMn(μdppO2)4MnX]2+2X-· 4MeOH·Me2CO [X = Cl, Br, I; dppO2 = 1,3-bis(diphenylphosphinoyl)propane], have been structurally characterised using single-crystal X-ray diffraction and shown to have increasing affinity for SO2 across the series C1 <Br <I via thermogravimetric measurements.

Original language	English
Pages (from-to)	1764-1765
Number of pages	1
Journal	Chemical Communications
Issue number	18
DOIs	https://doi.org/10.1039/b101263k
Publication status	Published - 21 Sept 2001

Keywords

Crystal structure; Molecular structure (of manganese diphosphinoylpropane halo dinuclear 'Chinese lantern' complex)

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abstract = "Three new 'Chinese lantern' complexes [XMn(μdppO2)4MnX]2+2X-· 4MeOH·Me2CO [X = Cl, Br, I; dppO2 = 1,3-bis(diphenylphosphinoyl)propane], have been structurally characterised using single-crystal X-ray diffraction and shown to have increasing affinity for SO2 across the series C1 ",

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AU - Cross, W. I.

AU - Godfrey, S. M.

AU - McAuliffe, C. A.

AU - Pritchard, R. G.

PY - 2001/9/21

Y1 - 2001/9/21

N2 - Three new 'Chinese lantern' complexes [XMn(μdppO2)4MnX]2+2X-· 4MeOH·Me2CO [X = Cl, Br, I; dppO2 = 1,3-bis(diphenylphosphinoyl)propane], have been structurally characterised using single-crystal X-ray diffraction and shown to have increasing affinity for SO2 across the series C1

AB - Three new 'Chinese lantern' complexes [XMn(μdppO2)4MnX]2+2X-· 4MeOH·Me2CO [X = Cl, Br, I; dppO2 = 1,3-bis(diphenylphosphinoyl)propane], have been structurally characterised using single-crystal X-ray diffraction and shown to have increasing affinity for SO2 across the series C1

KW - Crystal structure; Molecular structure (of manganese diphosphinoylpropane halo dinuclear 'Chinese lantern' complex)

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UR - https://www.ccdc.cam.ac.uk/structures/search?id=doi:10.5517/cc549f0&sid=DataCite

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EP - 1765

JO - Chemical Communications

JF - Chemical Communications

IS - 18

ER -

Crystal engineering of microporous 'Chinese-lantern' compounds to improve their ability to reversibly adsorb sulfur dioxide

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