Crystal engineering: the effects of π–π interactions incopper(i) and silver(i) complexes of 2,7-diazapyrene

Martin Schroder; A J Blake; M Schröder; N R Champness; A N Khlobystov; D A Lemenovskii; W-S Li

doi:10.1039/A702050C

Crystal engineering: the effects of π–π interactions incopper(i) and silver(i) complexes of 2,7-diazapyrene

Martin Schroder, A J Blake, M Schröder, N R Champness, A N Khlobystov, D A Lemenovskii, W-S Li

Research output: Contribution to journal › Article › peer-review

Abstract

The ligand 2,7-diazapyrene (L) is used to construct three- and two-dimensional arrays with Cu I and Ag I ions: {[Cu I L 2 ]PF 6 }= shows an adamantoid network with three interpenetrating networks, while {[Ag I L 2 (MeCN) 2 ]BF 4 } ∞ forms linear chains of [AgL] = units linked by apparent π–π stacking and Ag···Ag interactions between adjacent diazapyrene ligands to form two-dimensional sheets.

Original language	English
Pages (from-to)	1339-1340
Number of pages	2
Journal	Chemical Communications
Issue number	15
DOIs	https://doi.org/10.1039/A702050C
Publication status	Published - 1997

Access to Document

10.1039/A702050C

http://www.scopus.com/inward/record.url?eid=2-s2.0-0002488530&partnerID=40&md5=4a0f2e4124fe8fbd5ed1f56cbae25ca6

Cite this

@article{b79072e145ab44e0abe82aa60c6378b8,

title = "Crystal engineering: the effects of π–π interactions incopper(i) and silver(i) complexes of 2,7-diazapyrene",

abstract = "The ligand 2,7-diazapyrene (L) is used to construct three- and two-dimensional arrays with Cu I and Ag I ions: {[Cu I L 2 ]PF 6 }= shows an adamantoid network with three interpenetrating networks, while {[Ag I L 2 (MeCN) 2 ]BF 4 } ∞ forms linear chains of [AgL] = units linked by apparent π–π stacking and Ag···Ag interactions between adjacent diazapyrene ligands to form two-dimensional sheets.",

author = "Martin Schroder and Blake, {A J} and M Schr{\"o}der and Champness, {N R} and Khlobystov, {A N} and Lemenovskii, {D A} and W-S Li",

note = "cited By 120",

year = "1997",

doi = "10.1039/A702050C",

language = "English",

pages = "1339--1340",

journal = "Chemical Communications",

issn = "1364-548X",

publisher = "Royal Society of Chemistry",

number = "15",

}

TY - JOUR

T1 - Crystal engineering: the effects of π–π interactions incopper(i) and silver(i) complexes of 2,7-diazapyrene

AU - Schroder, Martin

AU - Blake, A J

AU - Schröder, M

AU - Champness, N R

AU - Khlobystov, A N

AU - Lemenovskii, D A

AU - Li, W-S

N1 - cited By 120

PY - 1997

Y1 - 1997

N2 - The ligand 2,7-diazapyrene (L) is used to construct three- and two-dimensional arrays with Cu I and Ag I ions: {[Cu I L 2 ]PF 6 }= shows an adamantoid network with three interpenetrating networks, while {[Ag I L 2 (MeCN) 2 ]BF 4 } ∞ forms linear chains of [AgL] = units linked by apparent π–π stacking and Ag···Ag interactions between adjacent diazapyrene ligands to form two-dimensional sheets.

AB - The ligand 2,7-diazapyrene (L) is used to construct three- and two-dimensional arrays with Cu I and Ag I ions: {[Cu I L 2 ]PF 6 }= shows an adamantoid network with three interpenetrating networks, while {[Ag I L 2 (MeCN) 2 ]BF 4 } ∞ forms linear chains of [AgL] = units linked by apparent π–π stacking and Ag···Ag interactions between adjacent diazapyrene ligands to form two-dimensional sheets.

U2 - 10.1039/A702050C

DO - 10.1039/A702050C

M3 - Article

SN - 1364-548X

SP - 1339

EP - 1340

JO - Chemical Communications

JF - Chemical Communications

IS - 15

ER -

Crystal engineering: the effects of π–π interactions incopper(i) and silver(i) complexes of 2,7-diazapyrene

Abstract

Access to Document

Fingerprint

Cite this