Dearomative Cascade Photocatalysis: Divergent Synthesis through Catalyst Selective Energy Transfer

Michael J. James; Jonas Luca Schwarz; Felix Strieth-kalthoff; Birgit Wibbeling; Frank Glorius

doi:10.1021/jacs.8b03302

Dearomative Cascade Photocatalysis: Divergent Synthesis through Catalyst Selective Energy Transfer

Michael J. James
, Jonas Luca Schwarz
, Felix Strieth-kalthoff
, Birgit Wibbeling
, Frank Glorius

Organic Chemistry Group

University of Munster (Westfalische Wilhelms Universitat Munster)

Research output: Contribution to journal › Article › peer-review

Abstract

The discovery and application of dearomative cascade photocatalysis as a strategy in complex molecule synthesis is described. Visible-light-absorbing photosensitizers were used to (sequentially) activate a 1-naphthol derived arene precursor to divergently form two different polycyclic molecular scaffolds through catalyst selective energy transfer.

Original language	English
Pages (from-to)	8624-8628
Number of pages	5
Journal	Journal of the American Chemical Society
Volume	140
Issue number	28
DOIs	https://doi.org/10.1021/jacs.8b03302
Publication status	Published - 1 Jul 2018

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10.1021/jacs.8b03302

https://pubs.acs.org/doi/10.1021/jacs.8b03302

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title = "Dearomative Cascade Photocatalysis: Divergent Synthesis through Catalyst Selective Energy Transfer",

abstract = "The discovery and application of dearomative cascade photocatalysis as a strategy in complex molecule synthesis is described. Visible-light-absorbing photosensitizers were used to (sequentially) activate a 1-naphthol derived arene precursor to divergently form two different polycyclic molecular scaffolds through catalyst selective energy transfer.",

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AU - James, Michael J.

AU - Schwarz, Jonas Luca

AU - Strieth-kalthoff, Felix

AU - Wibbeling, Birgit

AU - Glorius, Frank

PY - 2018/7/1

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AB - The discovery and application of dearomative cascade photocatalysis as a strategy in complex molecule synthesis is described. Visible-light-absorbing photosensitizers were used to (sequentially) activate a 1-naphthol derived arene precursor to divergently form two different polycyclic molecular scaffolds through catalyst selective energy transfer.

U2 - 10.1021/jacs.8b03302

DO - 10.1021/jacs.8b03302

M3 - Article

SN - 0002-7863

VL - 140

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EP - 8628

JO - Journal of the American Chemical Society

JF - Journal of the American Chemical Society

IS - 28

ER -

Dearomative Cascade Photocatalysis: Divergent Synthesis through Catalyst Selective Energy Transfer

Abstract

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