Dehydropolymerization of H3B·NMeH2 Mediated by Cationic Iridium(III) Precatalysts Bearing κ3-iPr-PNRP Pincer Ligands (R = H, Me): An Unexpected Inner-Sphere Mechanism

Claire N. Brodie; Lia Sotorrios; Timothy M. Boyd; Stuart A. Macgregor; Andrew S. Weller

doi:10.1021/acscatal.2c03778

Dehydropolymerization of H3B·NMeH2 Mediated by Cationic Iridium(III) Precatalysts Bearing κ3-iPr-PNRP Pincer Ligands (R = H, Me): An Unexpected Inner-Sphere Mechanism

Claire N. Brodie, Lia Sotorrios, Timothy M. Boyd, Stuart A. Macgregor, Andrew S. Weller

Pharmacy

Research output: Contribution to journal › Article › peer-review

Original language	English
Pages (from-to)	13050–13064
Journal	ACS Catalysis
Volume	12
Issue number	20
DOIs	https://doi.org/10.1021/acscatal.2c03778
Publication status	Published - 21 Oct 2022

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10.1021/acscatal.2c03778

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title = "Dehydropolymerization of H3B·NMeH2 Mediated by Cationic Iridium(III) Precatalysts Bearing κ3-iPr-PNRP Pincer Ligands (R = H, Me): An Unexpected Inner-Sphere Mechanism",

author = "Brodie, {Claire N.} and Lia Sotorrios and Boyd, {Timothy M.} and Macgregor, {Stuart A.} and Weller, {Andrew S.}",

year = "2022",

month = oct,

day = "21",

doi = "10.1021/acscatal.2c03778",

language = "English",

volume = "12",

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T1 - Dehydropolymerization of H3B·NMeH2 Mediated by Cationic Iridium(III) Precatalysts Bearing κ3-iPr-PNRP Pincer Ligands (R = H, Me): An Unexpected Inner-Sphere Mechanism

AU - Brodie, Claire N.

AU - Sotorrios, Lia

AU - Boyd, Timothy M.

AU - Macgregor, Stuart A.

AU - Weller, Andrew S.

PY - 2022/10/21

Y1 - 2022/10/21

UR - https://doi.org/10.1021/acscatal.2c03778

U2 - 10.1021/acscatal.2c03778

DO - 10.1021/acscatal.2c03778

M3 - Article

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SP - 13050

EP - 13064

JO - ACS Catalysis

JF - ACS Catalysis

IS - 20

ER -

Dehydropolymerization of H3B·NMeH2 Mediated by Cationic Iridium(III) Precatalysts Bearing κ3-iPr-PNRP Pincer Ligands (R = H, Me): An Unexpected Inner-Sphere Mechanism

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