Delaminated CoAl-Layered Double Hydroxide@TiO2Heterojunction Nanocomposites for Photocatalytic Reduction of CO2

Photocatalytic reduction offers an attractive route for CO2utilization as a chemical feedstock for solar fuels production but remains challenging due to the poor efficiency, instability, and/or toxicity of current catalyst systems. Delaminated CoAl-layered double hydroxide nanosheets (LDH-DS) combined with TiO2nanotubes (NTs) or nanoparticles (NPs) are promising nanocomposite photocatalysts for CO2reduction. Heterojunction formation between visible light absorbing delaminated CoAl nanosheets and UV light absorbing TiO2nanotubes greatly enhances interfacial contact between both high aspect ratio components relative to their bulk counterparts. The resulting synergic interaction confers a significant improvement in photoinduced charge carrier separation, and concomitant aqueous phase CO2photocatalytic reduction, in the absence of a sacrificial hole acceptor. CO productivity for a 3 wt% LDH-DS@TiO2-NT nanocomposite of 4.57 µmol gcat-1h-1exhibits a tenfold and fivefold increase over that obtained for individual TiO2NT and delaminated CoAl-LDH components respectively and is double that obtained for 3 wt% bulk-LDH@TiO2-NT and 3 wt% LDH-DS@TiO2-NP catalysts. Synthesis of delaminated LDH and metal oxide nanocomposites represents a cost-effective strategy for aqueous phase CO2reduction.