Denitrative Sulfonylation of Nitroarenes with Sodium Sulfinates

Jonathan Da Luz; Michaela Čierna; Bradley Cooper; Thomas Harris; Ethan Lim; Jonathan R. Carney; Michael James

doi:10.1055/a-2295-8639

Denitrative Sulfonylation of Nitroarenes with Sodium Sulfinates

Jonathan Da Luz
, Michaela Čierna
, Bradley Cooper
, Thomas Harris
, Ethan Lim
, Jonathan R. Carney
, Michael James

Research output: Contribution to journal › Article › peer-review

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Abstract

A one-step method to convert nitroarenes into aryl sulfones under operationally simple, transition-metal-free conditions is described. A range of nitroarenes were reacted with sodium sulfinates and caesium carbonate in N,N′-dimethylpropyleneurea to afford aryl sulfones in up to 83% yield.

Original language	English
Journal	Synthesis
Volume	56
Issue number	21
Early online date	15 Apr 2024
DOIs	https://doi.org/10.1055/a-2295-8639
Publication status	Published - Nov 2024

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Denitrative SuflonylationAccepted author manuscript, 769 KBLicence: CC BY

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title = "Denitrative Sulfonylation of Nitroarenes with Sodium Sulfinates",

abstract = "A one-step method to convert nitroarenes into aryl sulfones under operationally simple, transition-metal-free conditions is described. A range of nitroarenes were reacted with sodium sulfinates and caesium carbonate in N,N′-dimethylpropyleneurea to afford aryl sulfones in up to 83\% yield.",

author = "Luz, \{Jonathan Da\} and Michaela {\v C}ierna and Bradley Cooper and Thomas Harris and Ethan Lim and Carney, \{Jonathan R.\} and Michael James",

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T1 - Denitrative Sulfonylation of Nitroarenes with Sodium Sulfinates

AU - Luz, Jonathan Da

AU - Čierna, Michaela

AU - Cooper, Bradley

AU - Harris, Thomas

AU - Lim, Ethan

AU - Carney, Jonathan R.

AU - James, Michael

PY - 2024/11

Y1 - 2024/11

N2 - A one-step method to convert nitroarenes into aryl sulfones under operationally simple, transition-metal-free conditions is described. A range of nitroarenes were reacted with sodium sulfinates and caesium carbonate in N,N′-dimethylpropyleneurea to afford aryl sulfones in up to 83% yield.

AB - A one-step method to convert nitroarenes into aryl sulfones under operationally simple, transition-metal-free conditions is described. A range of nitroarenes were reacted with sodium sulfinates and caesium carbonate in N,N′-dimethylpropyleneurea to afford aryl sulfones in up to 83% yield.

U2 - 10.1055/a-2295-8639

DO - 10.1055/a-2295-8639

M3 - Article

SN - 0039-7881

VL - 56

JO - Synthesis

JF - Synthesis

IS - 21

ER -

Denitrative Sulfonylation of Nitroarenes with Sodium Sulfinates

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