Direct synthesis of sulfonated azacalixarenes in water

Jonathan Clayden; Stephen J M Rowbottom; Warren J. Ebenezer; Michael G. Hutchings

doi:10.1039/b911631a

Direct synthesis of sulfonated azacalixarenes in water

Jonathan Clayden, Stephen J M Rowbottom, Warren J. Ebenezer, Michael G. Hutchings

Research output: Contribution to journal › Article › peer-review

Abstract

Successive treatment of cyanuric chloride with two aromatic diamines, at least one of them sulfonated, yields water-soluble sulfonated azacalix[4]arenes which may be isolated by crystallisation. Functionalised azacalixarenes may be made by first displacing two chloro substituents from the cyclisation precursor. Attempted formation of an azacalix[6]arene led to a dimeric species for which two structures may be proposed, one of them an azacalixarene catenane. © The Royal Society of Chemistry 2009.

Original language	English
Pages (from-to)	4871-4880
Number of pages	9
Journal	Organic and Biomolecular Chemistry
Volume	7
Issue number	23
DOIs	https://doi.org/10.1039/b911631a
Publication status	Published - 2009

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title = "Direct synthesis of sulfonated azacalixarenes in water",

abstract = "Successive treatment of cyanuric chloride with two aromatic diamines, at least one of them sulfonated, yields water-soluble sulfonated azacalix[4]arenes which may be isolated by crystallisation. Functionalised azacalixarenes may be made by first displacing two chloro substituents from the cyclisation precursor. Attempted formation of an azacalix[6]arene led to a dimeric species for which two structures may be proposed, one of them an azacalixarene catenane. {\textcopyright} The Royal Society of Chemistry 2009.",

author = "Jonathan Clayden and Rowbottom, {Stephen J M} and Ebenezer, {Warren J.} and Hutchings, {Michael G.}",

year = "2009",

doi = "10.1039/b911631a",

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pages = "4871--4880",

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publisher = "Royal Society of Chemistry",

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AU - Clayden, Jonathan

AU - Rowbottom, Stephen J M

AU - Ebenezer, Warren J.

AU - Hutchings, Michael G.

PY - 2009

Y1 - 2009

N2 - Successive treatment of cyanuric chloride with two aromatic diamines, at least one of them sulfonated, yields water-soluble sulfonated azacalix[4]arenes which may be isolated by crystallisation. Functionalised azacalixarenes may be made by first displacing two chloro substituents from the cyclisation precursor. Attempted formation of an azacalix[6]arene led to a dimeric species for which two structures may be proposed, one of them an azacalixarene catenane. © The Royal Society of Chemistry 2009.

AB - Successive treatment of cyanuric chloride with two aromatic diamines, at least one of them sulfonated, yields water-soluble sulfonated azacalix[4]arenes which may be isolated by crystallisation. Functionalised azacalixarenes may be made by first displacing two chloro substituents from the cyclisation precursor. Attempted formation of an azacalix[6]arene led to a dimeric species for which two structures may be proposed, one of them an azacalixarene catenane. © The Royal Society of Chemistry 2009.

U2 - 10.1039/b911631a

DO - 10.1039/b911631a

M3 - Article

VL - 7

SP - 4871

EP - 4880

JO - Organic & biomolecular chemistry

JF - Organic & biomolecular chemistry

SN - 1477-0520

IS - 23

ER -

Direct synthesis of sulfonated azacalixarenes in water

Abstract

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