Directed synthesis of {Mn18Cu6} heterometallic complexes

Victoria A. Milway; Floriana Tuna; Andrew R. Farrell; Laura E. Sharp; Simon Parsons; Mark Murrie

doi:10.1002/anie.201208781

Directed synthesis of {Mn18Cu6} heterometallic complexes

Victoria A. Milway, Floriana Tuna, Andrew R. Farrell, Laura E. Sharp, Simon Parsons, Mark Murrie

Research output: Contribution to journal › Article › peer-review

Abstract

A two-step method for the directed synthesis of high-nuclearity Mn III-MnII-CuII heterometallic transition metal complexes is described. The synthesis starts from a preformed copper(II) complex to trap an inner hexacapped cuboctahedral manganese oxide core. Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Original language	English
Pages (from-to)	1949-1952
Number of pages	3
Journal	Angewandte Chemie - International Edition
Volume	52
Issue number	7
DOIs	https://doi.org/10.1002/anie.201208781
Publication status	Published - 11 Feb 2013

Keywords

copper
heterometallic complexes
magnetic properties
manganese
polynuclear clusters

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10.1002/anie.201208781

CCDC 907990: Experimental Crystal Structure Determination
Milway, V. A. (Contributor), Tuna, F. (Contributor), Farrell, A. R. (Contributor), Sharp, L. E. (Contributor), Parsons, S. (Contributor) & Murrie, M. (Contributor), Cambridge Crystallographic Data Centre, 1 Jan 2013
DOI: 10.5517/cczgv08, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/cczgv08&sid=DataCite
Dataset
CCDC 907991: Experimental Crystal Structure Determination
Milway, V. A. (Contributor), Tuna, F. (Contributor), Farrell, A. R. (Contributor), Sharp, L. E. (Contributor), Parsons, S. (Contributor) & Murrie, M. (Contributor), Cambridge Crystallographic Data Centre, 1 Jan 2013
DOI: 10.5517/cczgv19, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/cczgv19&sid=DataCite
Dataset
CCDC 907989: Experimental Crystal Structure Determination
Milway, V. A. (Contributor), Tuna, F. (Contributor), Farrell, A. R. (Contributor), Sharp, L. E. (Contributor), Parsons, S. (Contributor) & Murrie, M. (Contributor), Cambridge Crystallographic Data Centre, 1 Jan 2013
DOI: 10.5517/cczgtz6, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/cczgtz6&sid=DataCite
Dataset

Cite this

@article{1c21d75ae91e49929fbb7ba1fce4544d,

title = "Directed synthesis of {Mn18Cu6} heterometallic complexes",

abstract = "A two-step method for the directed synthesis of high-nuclearity Mn III-MnII-CuII heterometallic transition metal complexes is described. The synthesis starts from a preformed copper(II) complex to trap an inner hexacapped cuboctahedral manganese oxide core. Copyright {\textcopyright} 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.",

keywords = "copper, heterometallic complexes, magnetic properties, manganese, polynuclear clusters",

author = "Milway, {Victoria A.} and Floriana Tuna and Farrell, {Andrew R.} and Sharp, {Laura E.} and Simon Parsons and Mark Murrie",

year = "2013",

month = feb,

day = "11",

doi = "10.1002/anie.201208781",

language = "English",

volume = "52",

pages = "1949--1952",

journal = "Angewandte Chemie. International Edition",

issn = "1433-7851",

publisher = "John Wiley & Sons Ltd",

number = "7",

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TY - JOUR

T1 - Directed synthesis of {Mn18Cu6} heterometallic complexes

AU - Milway, Victoria A.

AU - Tuna, Floriana

AU - Farrell, Andrew R.

AU - Sharp, Laura E.

AU - Parsons, Simon

AU - Murrie, Mark

PY - 2013/2/11

Y1 - 2013/2/11

N2 - A two-step method for the directed synthesis of high-nuclearity Mn III-MnII-CuII heterometallic transition metal complexes is described. The synthesis starts from a preformed copper(II) complex to trap an inner hexacapped cuboctahedral manganese oxide core. Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

AB - A two-step method for the directed synthesis of high-nuclearity Mn III-MnII-CuII heterometallic transition metal complexes is described. The synthesis starts from a preformed copper(II) complex to trap an inner hexacapped cuboctahedral manganese oxide core. Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

KW - copper

KW - heterometallic complexes

KW - magnetic properties

KW - manganese

KW - polynuclear clusters

U2 - 10.1002/anie.201208781

DO - 10.1002/anie.201208781

M3 - Article

VL - 52

SP - 1949

EP - 1952

JO - Angewandte Chemie. International Edition

JF - Angewandte Chemie. International Edition

SN - 1433-7851

IS - 7

ER -

Directed synthesis of {Mn18Cu6} heterometallic complexes

Abstract

Keywords

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Datasets

CCDC 907990: Experimental Crystal Structure Determination

CCDC 907991: Experimental Crystal Structure Determination

CCDC 907989: Experimental Crystal Structure Determination

Cite this