Dynamic ligand exchange in reactions of samarium diiodide

Dhandapani V. Sadasivam, Joseph A. Teprovich, David J. Procter, Robert A. Flowers

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    Abstract

    Mechanistic studies show the importance of iodide displacement by additives that accelerate reactions of samarium diiodide. The key feature important for acceleration of reaction rate is the use of proton donors and other additives that have a high enough affinity for Sm(II) to displace iodide yet do not saturate the coordination sphere inhibiting substrate reduction. © 2010 American Chemical Society.
    Original languageEnglish
    Pages (from-to)4140-4143
    Number of pages3
    JournalOrganic Letters
    Volume12
    Issue number18
    DOIs
    Publication statusPublished - 17 Sep 2010

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