Edge reactivity and water-assisted dissociation on cobalt oxide nanoislands

J. Fester, M. García-Melchor, A. S. Walton, M. Bajdich, Z. Li, L. Lammich, A. Vojvodic, J. V. Lauritsen

    Research output: Contribution to journalArticlepeer-review


    Transition metal oxides show great promise as Earth-abundant catalysts for the oxygen evolution reaction in electrochemical water splitting. However, progress in the development of highly active oxide nanostructures is hampered by a lack of knowledge of the location and nature of the active sites. Here we show, through atom-resolved scanning tunnelling microscopy, X-ray spectroscopy and computational modelling, how hydroxyls form from water dissociation at under coordinated cobalt edge sites of cobalt oxide nanoislands. Surprisingly, we find that an additional water molecule acts to promote all the elementary steps of the dissociation process and subsequent hydrogen migration, revealing the important assisting role of a water molecule in its own dissociation process on a metal oxide. Inspired by the experimental findings, we theoretically model the oxygen evolution reaction activity of cobalt oxide nanoislands and show that the nanoparticle metal edges also display favourable adsorption energetics for water oxidation under electrochemical conditions.
    Original languageEnglish
    Pages (from-to)14169 EP -
    JournalNature Communications
    Early online date30 Jan 2017
    Publication statusPublished - 2017


    • Electrocatalysis
    • Scanning probe microscopy
    • Surfaces, interfaces and thin films
    • XPS


    Dive into the research topics of 'Edge reactivity and water-assisted dissociation on cobalt oxide nanoislands'. Together they form a unique fingerprint.

    Cite this