Effective binuclear Pd(II) complexes for Suzuki reactions in water

Murat Emre Hanhan; Cemil Cetinkaya; Michael P. Shaver

doi:10.1002/aoc.3034

Effective binuclear Pd(II) complexes for Suzuki reactions in water

Murat Emre Hanhan, Cemil Cetinkaya, Michael P. Shaver

Research output: Contribution to journal › Article › peer-review

Abstract

A series of new ionic binuclear Pd(II) complexes supported by water-soluble bis(-diimine) ligands were prepared and employed as catalysts for the palladium-catalyzed Suzuki reaction in aqueous media. The binuclear nature of the complexes increased the reaction rate, while electronic and steric modification of the ligand frameworks had a remarkable influence upon the catalytic activity of the palladium complexes. The catalysts were shown to be homogeneous through mercury poisoning experiments and complexes could be recycled more than 10 times without loss of catalytic activity. Copyright (c) 2013 John Wiley & Sons, Ltd.

Original language	English
Pages (from-to)	570-577
Number of pages	8
Journal	Applied Organometallic Chemistry
Volume	27
Issue number	10
DOIs	https://doi.org/10.1002/aoc.3034
Publication status	Published - Oct 2013

Keywords

Suzuki coupling
palladium
diimine
aqueous media
CROSS-COUPLING REACTIONS
AQUEOUS ORGANOMETALLIC CHEMISTRY
METAL-METAL INTERACTIONS
ARYL CHLORIDES
CATALYZED SUZUKI
HETEROGENEOUS CATALYSIS
PALLADIUM(II) COMPLEXES
THERMAL-DECOMPOSITION
DIIMINE COMPLEXES
ARYLBORONIC ACIDS

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

Access to Document

10.1002/aoc.3034

Cite this

@article{9ee94bc9152849b7a90677ace6b8f6f3,

title = "Effective binuclear Pd(II) complexes for Suzuki reactions in water",

abstract = "A series of new ionic binuclear Pd(II) complexes supported by water-soluble bis(-diimine) ligands were prepared and employed as catalysts for the palladium-catalyzed Suzuki reaction in aqueous media. The binuclear nature of the complexes increased the reaction rate, while electronic and steric modification of the ligand frameworks had a remarkable influence upon the catalytic activity of the palladium complexes. The catalysts were shown to be homogeneous through mercury poisoning experiments and complexes could be recycled more than 10 times without loss of catalytic activity. Copyright (c) 2013 John Wiley & Sons, Ltd.",

keywords = "Suzuki coupling, palladium, diimine, aqueous media, CROSS-COUPLING REACTIONS, AQUEOUS ORGANOMETALLIC CHEMISTRY, METAL-METAL INTERACTIONS, ARYL CHLORIDES, CATALYZED SUZUKI, HETEROGENEOUS CATALYSIS, PALLADIUM(II) COMPLEXES, THERMAL-DECOMPOSITION, DIIMINE COMPLEXES, ARYLBORONIC ACIDS",

author = "Hanhan, {Murat Emre} and Cemil Cetinkaya and Shaver, {Michael P.}",

year = "2013",

month = oct,

doi = "10.1002/aoc.3034",

language = "English",

volume = "27",

pages = "570--577",

journal = "Applied Organometallic Chemistry",

issn = "0268-2605",

publisher = "John Wiley & Sons Ltd",

number = "10",

}

TY - JOUR

T1 - Effective binuclear Pd(II) complexes for Suzuki reactions in water

AU - Hanhan, Murat Emre

AU - Cetinkaya, Cemil

AU - Shaver, Michael P.

PY - 2013/10

Y1 - 2013/10

N2 - A series of new ionic binuclear Pd(II) complexes supported by water-soluble bis(-diimine) ligands were prepared and employed as catalysts for the palladium-catalyzed Suzuki reaction in aqueous media. The binuclear nature of the complexes increased the reaction rate, while electronic and steric modification of the ligand frameworks had a remarkable influence upon the catalytic activity of the palladium complexes. The catalysts were shown to be homogeneous through mercury poisoning experiments and complexes could be recycled more than 10 times without loss of catalytic activity. Copyright (c) 2013 John Wiley & Sons, Ltd.

AB - A series of new ionic binuclear Pd(II) complexes supported by water-soluble bis(-diimine) ligands were prepared and employed as catalysts for the palladium-catalyzed Suzuki reaction in aqueous media. The binuclear nature of the complexes increased the reaction rate, while electronic and steric modification of the ligand frameworks had a remarkable influence upon the catalytic activity of the palladium complexes. The catalysts were shown to be homogeneous through mercury poisoning experiments and complexes could be recycled more than 10 times without loss of catalytic activity. Copyright (c) 2013 John Wiley & Sons, Ltd.

KW - Suzuki coupling

KW - palladium

KW - diimine

KW - aqueous media

KW - CROSS-COUPLING REACTIONS

KW - AQUEOUS ORGANOMETALLIC CHEMISTRY

KW - METAL-METAL INTERACTIONS

KW - ARYL CHLORIDES

KW - CATALYZED SUZUKI

KW - HETEROGENEOUS CATALYSIS

KW - PALLADIUM(II) COMPLEXES

KW - THERMAL-DECOMPOSITION

KW - DIIMINE COMPLEXES

KW - ARYLBORONIC ACIDS

U2 - 10.1002/aoc.3034

DO - 10.1002/aoc.3034

M3 - Article

SN - 0268-2605

VL - 27

SP - 570

EP - 577

JO - Applied Organometallic Chemistry

JF - Applied Organometallic Chemistry

IS - 10

ER -

Effective binuclear Pd(II) complexes for Suzuki reactions in water

Abstract

Keywords

UN SDGs

Access to Document

Fingerprint

Cite this