Electrochemical rate constants in room temperature ionic liquids: The oxidation of a series of ferrocene derivatives

Nicole Fietkau; Antony D. Clegg; Russell G. Evans; Constanza Villagrán; Christopher Hardacre; Richard G. Compton

doi:10.1002/cphc.200500709

Electrochemical rate constants in room temperature ionic liquids: The oxidation of a series of ferrocene derivatives

Nicole Fietkau, Antony D. Clegg, Russell G. Evans, Constanza Villagrán, Christopher Hardacre, Richard G. Compton

Research output: Contribution to journal › Article › peer-review

Abstract

The high-speed channel electrode has been used to measure heterogeneous electron-transfer rates, k₀, for a series of ferrocene derivatives in room temperaure ionic liquids (RTILs) under steady-state conditions thus avoiding the problems of ohmic drop and capacitative currents associated with transient methods. The figure shows the three-dimensional surface plot for k₀ versus the transfer coefficient, α.

Original language	English
Pages (from-to)	1041-1045
Number of pages	5
Journal	ChemPhysChem
Volume	7
Issue number	5
DOIs	https://doi.org/10.1002/cphc.200500709
Publication status	Published - 12 May 2006

Keywords

Electrochemistry
Electron transfer
Ferrocene derivatives
Heterogeneous rate constants
Ionic liquids

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abstract = "The high-speed channel electrode has been used to measure heterogeneous electron-transfer rates, k0, for a series of ferrocene derivatives in room temperaure ionic liquids (RTILs) under steady-state conditions thus avoiding the problems of ohmic drop and capacitative currents associated with transient methods. The figure shows the three-dimensional surface plot for k0 versus the transfer coefficient, α.",

keywords = "Electrochemistry, Electron transfer, Ferrocene derivatives, Heterogeneous rate constants, Ionic liquids",

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AU - Evans, Russell G.

AU - Villagrán, Constanza

AU - Hardacre, Christopher

AU - Compton, Richard G.

PY - 2006/5/12

Y1 - 2006/5/12

N2 - The high-speed channel electrode has been used to measure heterogeneous electron-transfer rates, k0, for a series of ferrocene derivatives in room temperaure ionic liquids (RTILs) under steady-state conditions thus avoiding the problems of ohmic drop and capacitative currents associated with transient methods. The figure shows the three-dimensional surface plot for k0 versus the transfer coefficient, α.

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KW - Electrochemistry

KW - Electron transfer

KW - Ferrocene derivatives

KW - Heterogeneous rate constants

KW - Ionic liquids

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Electrochemical rate constants in room temperature ionic liquids: The oxidation of a series of ferrocene derivatives

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