TY - JOUR
T1 - Electrochemistry in room-temperature ionic liquids
T2 - potential windows at mercury electrodes
AU - Rogers, E. I.
AU - S̃ljukic, Biljana
AU - Hardacre, Christopher
AU - Compton, R. G.
PY - 2009/7/9
Y1 - 2009/7/9
N2 - The cathodic and anodic potential limits of eleven different ionic liquids were determined at a mercury hemisphere electrode. Ionic liquids containing the phosphonium cation (tri(n-hexyl)tetradecylphosphonium, [P14,6,6,6]+) give the largest potential window, especially when coupled to a trifluorotris(pentafluoroethyl)- phosphate, [FAP]-, or bis(trifluoromethanesulfonyl)imide, [NTf2]-, anion.
AB - The cathodic and anodic potential limits of eleven different ionic liquids were determined at a mercury hemisphere electrode. Ionic liquids containing the phosphonium cation (tri(n-hexyl)tetradecylphosphonium, [P14,6,6,6]+) give the largest potential window, especially when coupled to a trifluorotris(pentafluoroethyl)- phosphate, [FAP]-, or bis(trifluoromethanesulfonyl)imide, [NTf2]-, anion.
UR - http://www.scopus.com/inward/record.url?scp=67849101187&partnerID=8YFLogxK
U2 - 10.1021/je800898z
DO - 10.1021/je800898z
M3 - Article
AN - SCOPUS:67849101187
SN - 0021-9568
VL - 54
SP - 2049
EP - 2053
JO - Journal of Chemical & Engineering Data
JF - Journal of Chemical & Engineering Data
IS - 7
ER -