Enhanced proton conductivity in a flexible metal-organic framework promoted by single-crystal-to-single-crystal transformation.

Xi Chen; Zhongyue Zhang; Jin Chen; Sergei Sapchenko; Xue Han; Ivan Da Silva; Ming Li; Inigo Vitorica-yrzebal; George F. S. Whitehead; Chiu Chung Tang; Kunio Awaga; Sihai Yang; Martin Schroder

doi:10.1039/D0CC05270A

Enhanced proton conductivity in a flexible metal-organic framework promoted by single-crystal-to-single-crystal transformation.

Xi Chen, Zhongyue Zhang, Jin Chen, Sergei Sapchenko, Xue Han, Ivan Da Silva, Ming Li, Inigo Vitorica-yrzebal, George F. S. Whitehead, Chiu Chung Tang, Kunio Awaga, Sihai Yang, Martin Schroder

Research output: Contribution to journal › Article › peer-review

7 Downloads (Pure)

Abstract

MFM-722(Pb)-DMA undergoes a single-crystal-to-single-crystal (SCSC) transformation to give MFM-722(Pb)-H2O via ligand substitution upon exposure to water vapour. In situ single crystal impedance spectroscopy reveals an increase in proton conductivity due to this structural transition, with MFM-722(Pb)-H2O showing a proton conductivity of 6.61×10-4 S cm-1 at 50 °C and 98% RH. The low activation energy (Ea = 0.21 eV) indicates that the proton conduction follows a Grotthuss mechanism.

Original language	English
Journal	Chemical Communications
Early online date	17 Nov 2020
DOIs	https://doi.org/10.1039/D0CC05270A
Publication status	E-pub ahead of print - 17 Nov 2020

Access to Document

10.1039/D0CC05270A

Manuscript in template shortenedAccepted author manuscript, 881 KB

http://pubs.rsc.org/en/Content/ArticleLanding/2020/CC/D0CC05270A

Cite this

Chen, X., Zhang, Z., Chen, J., Sapchenko, S., Han, X., Da Silva, I., Li, M., Vitorica-yrzebal, I., Whitehead, G. F. S., Tang, C. C., Awaga, K., Yang, S., & Schroder, M. (2020). Enhanced proton conductivity in a flexible metal-organic framework promoted by single-crystal-to-single-crystal transformation. Chemical Communications. Advance online publication. https://doi.org/10.1039/D0CC05270A

@article{2bc1217587c44b81a2d1ac73895e6205,

title = "Enhanced proton conductivity in a flexible metal-organic framework promoted by single-crystal-to-single-crystal transformation.",

abstract = "MFM-722(Pb)-DMA undergoes a single-crystal-to-single-crystal (SCSC) transformation to give MFM-722(Pb)-H2O via ligand substitution upon exposure to water vapour. In situ single crystal impedance spectroscopy reveals an increase in proton conductivity due to this structural transition, with MFM-722(Pb)-H2O showing a proton conductivity of 6.61×10-4 S cm-1 at 50 °C and 98% RH. The low activation energy (Ea = 0.21 eV) indicates that the proton conduction follows a Grotthuss mechanism.",

author = "Xi Chen and Zhongyue Zhang and Jin Chen and Sergei Sapchenko and Xue Han and {Da Silva}, Ivan and Ming Li and Inigo Vitorica-yrzebal and Whitehead, {George F. S.} and Tang, {Chiu Chung} and Kunio Awaga and Sihai Yang and Martin Schroder",

year = "2020",

month = nov,

day = "17",

doi = "10.1039/D0CC05270A",

language = "English",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

}

TY - JOUR

T1 - Enhanced proton conductivity in a flexible metal-organic framework promoted by single-crystal-to-single-crystal transformation.

AU - Chen, Xi

AU - Zhang, Zhongyue

AU - Chen, Jin

AU - Sapchenko, Sergei

AU - Han, Xue

AU - Da Silva, Ivan

AU - Li, Ming

AU - Vitorica-yrzebal, Inigo

AU - Whitehead, George F. S.

AU - Tang, Chiu Chung

AU - Awaga, Kunio

AU - Yang, Sihai

AU - Schroder, Martin

PY - 2020/11/17

Y1 - 2020/11/17

N2 - MFM-722(Pb)-DMA undergoes a single-crystal-to-single-crystal (SCSC) transformation to give MFM-722(Pb)-H2O via ligand substitution upon exposure to water vapour. In situ single crystal impedance spectroscopy reveals an increase in proton conductivity due to this structural transition, with MFM-722(Pb)-H2O showing a proton conductivity of 6.61×10-4 S cm-1 at 50 °C and 98% RH. The low activation energy (Ea = 0.21 eV) indicates that the proton conduction follows a Grotthuss mechanism.

AB - MFM-722(Pb)-DMA undergoes a single-crystal-to-single-crystal (SCSC) transformation to give MFM-722(Pb)-H2O via ligand substitution upon exposure to water vapour. In situ single crystal impedance spectroscopy reveals an increase in proton conductivity due to this structural transition, with MFM-722(Pb)-H2O showing a proton conductivity of 6.61×10-4 S cm-1 at 50 °C and 98% RH. The low activation energy (Ea = 0.21 eV) indicates that the proton conduction follows a Grotthuss mechanism.

U2 - 10.1039/D0CC05270A

DO - 10.1039/D0CC05270A

M3 - Article

SN - 1359-7345

JO - Chemical Communications

JF - Chemical Communications

ER -

Enhanced proton conductivity in a flexible metal-organic framework promoted by single-crystal-to-single-crystal transformation.

Abstract

Access to Document

Other files and links

Fingerprint

Cite this