Abstract
H-2 adsorption in (Me2NH2)[In(L)] is enhanced by exchange of Me2NH2+ for Li+ cations; the Li+-exchanged material displays a lower isosteric heat for H-2 adsorption than the parent material, indicating that the increase in H-2 capacity is due to an increase in the accessible pore volume on cation exchange, while the lower adsorption enthalpy is consistent with increased pore size.
| Original language | English |
|---|---|
| Pages (from-to) | 6108-6110 |
| Number of pages | 3 |
| Journal | Chemical Communications |
| Issue number | 46 |
| DOIs | |
| Publication status | Published - 2008 |
Keywords
- metal-organic frameworks
- hydrogen-storage
- mofs
- temperature
- capacity
- density
- binding
- cation
- sites
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CCDC 698649: Experimental Crystal Structure Determination
Yang, S. (Contributor), Lin, X. (Contributor), Blake, A. (Contributor), Thomas, K. M. (Contributor), Hubberstey, P. (Contributor), Champness, N. (Contributor) & Schröder, M. (Contributor), Cambridge Crystallographic Data Centre, 1 Jan 2009
DOI: 10.5517/ccrg028, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/ccrg028&sid=DataCite
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