Error analysis in the fitting of photoemission lineshapes using the Levenberg-Marquardt method

A. W. Robinson, P. Gardner, A. P J Stampfl, R. Martin, G. Nyberg

    Research output: Contribution to journalArticlepeer-review

    Abstract

    The problem of determining errors in the fitting of non-linear functions to photoemission spectra is considered. A simple method of determining the standard error on each fitting parameter is outlined, using the widely used Levenberg-Marquardt fitting method. This is discussed with reference to the fitting of Si 2p photoemission data, for Si-containing species adsorbed on the Cu{111} surface. A C/C++ algorithm for modelling multiple spin-orbit split doublet peaks with a Voigt lineshape is presented. © 1998 Elsevier Science B.V. All rights reserved.
    Original languageEnglish
    Pages (from-to)97-105
    Number of pages8
    JournalJournal of Electron Spectroscopy and Related Phenomena
    Volume94
    Issue number1-2
    Publication statusPublished - 30 Jun 1998

    Keywords

    • Errors
    • Fitting
    • Levenberg-Marquardt
    • Photoemission
    • Silicon

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