Evaporation and deposition of alkyl-capped silicon nanocrystals in ultrahigh vacuum

Yimin Chao, Lidija Šiller, Satheesh Krishnamurthy, Paul R. Coxon, Ursel Bangert, Mhairi Gass, Lisbeth Kjeldgaard, Samson N. Patole, Lars H. Lie, Norah O'Farrell, Thomas A. Alsop, Andrew Houlton, Benjamin R. Horrocks

    Research output: Contribution to journalArticlepeer-review

    Abstract

    Nanocrystals are under active investigation because of their interesting size-dependent properties and potential applications. Silicon nanocrystals have been studied for possible uses in optoelectronics, and may be relevant to the understanding of natural processes such as lightning strikes. Gas-phase methods can be used to prepare nanocrystals, and mass spectrometric techniques have been used to analyse Au and CdSe clusters. However, it is difficult to study nanocrystals by such methods unless they are synthesized in the gas phase. In particular, pre-prepared nanocrystals are generally difficult to sublime without decomposition. Here we report the observation that films of alkyl-capped silicon nanocrystals evaporate upon heating in ultrahigh vacuum at 200°C, and the vapour of intact nanocrystals can be collected on a variety of solid substrates. This effect may be useful for the controlled preparation of new quantum-confined silicon structures and could facilitate their mass spectroscopic study and size-selection. © 2007 Nature Publishing Group.
    Original languageEnglish
    Pages (from-to)486-489
    Number of pages3
    JournalNature Nanotechnology
    Volume2
    Issue number8
    DOIs
    Publication statusPublished - Aug 2007

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