Evidence consistent with a stepwise elimination-addition process for hydrolysis and aminolysis of aryl toluene-α-sulphonates

Andrew Williams; Kenneth T. Douglas; John S. Loran

doi:10.1039/C39740000689

Evidence consistent with a stepwise elimination-addition process for hydrolysis and aminolysis of aryl toluene-α-sulphonates

Andrew Williams^*, Kenneth T. Douglas, John S. Loran

^*Corresponding author for this work

Pharmacy

University of Kent

Research output: Contribution to journal › Article › peer-review

Abstract

The hydrolysis and aminolysis of substituted phenyl toluene-α- sulphonates possess a stepwise elimination-addition mechanism (E1cB) involving a sulphene intermediate; the E1cB pathway for the hydrolysis of 5-nitro-2-hydroxytoluene-α-sulphonic acid sultone is sterically suppressed.

Original language	English
Pages (from-to)	689-690
Number of pages	2
Journal	Journal of the Chemical Society, Chemical Communications
Issue number	17
DOIs	https://doi.org/10.1039/C39740000689
Publication status	Published - 1974

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title = "Evidence consistent with a stepwise elimination-addition process for hydrolysis and aminolysis of aryl toluene-α-sulphonates",

abstract = "The hydrolysis and aminolysis of substituted phenyl toluene-α- sulphonates possess a stepwise elimination-addition mechanism (E1cB) involving a sulphene intermediate; the E1cB pathway for the hydrolysis of 5-nitro-2-hydroxytoluene-α-sulphonic acid sultone is sterically suppressed.",

author = "Andrew Williams and Douglas, {Kenneth T.} and Loran, {John S.}",

year = "1974",

doi = "10.1039/C39740000689",

language = "English",

pages = "689--690",

journal = "Journal of the Chemical Society, Chemical Communications",

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publisher = "Chemical Society",

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T1 - Evidence consistent with a stepwise elimination-addition process for hydrolysis and aminolysis of aryl toluene-α-sulphonates

AU - Williams, Andrew

AU - Douglas, Kenneth T.

AU - Loran, John S.

PY - 1974

Y1 - 1974

N2 - The hydrolysis and aminolysis of substituted phenyl toluene-α- sulphonates possess a stepwise elimination-addition mechanism (E1cB) involving a sulphene intermediate; the E1cB pathway for the hydrolysis of 5-nitro-2-hydroxytoluene-α-sulphonic acid sultone is sterically suppressed.

AB - The hydrolysis and aminolysis of substituted phenyl toluene-α- sulphonates possess a stepwise elimination-addition mechanism (E1cB) involving a sulphene intermediate; the E1cB pathway for the hydrolysis of 5-nitro-2-hydroxytoluene-α-sulphonic acid sultone is sterically suppressed.

UR - http://www.scopus.com/inward/record.url?scp=37049136952&partnerID=8YFLogxK

U2 - 10.1039/C39740000689

DO - 10.1039/C39740000689

M3 - Article

AN - SCOPUS:37049136952

SN - 0022-4936

SP - 689

EP - 690

JO - Journal of the Chemical Society, Chemical Communications

JF - Journal of the Chemical Society, Chemical Communications

IS - 17

ER -

Evidence consistent with a stepwise elimination-addition process for hydrolysis and aminolysis of aryl toluene-α-sulphonates

Abstract

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