Evidence for an insertion-homolysis mechanism for carbon-sulphur bond formation in penicillin biosynthesis

Jack E. Baldwin; Robert M. Adlington; Daniel G. Marquess; Andrew R. Pitt; Andrew T. Russell

doi:10.1039/C39910000856

Evidence for an insertion-homolysis mechanism for carbon-sulphur bond formation in penicillin biosynthesis

Jack E. Baldwin^*, Robert M. Adlington, Daniel G. Marquess, Andrew R. Pitt, Andrew T. Russell

^*Corresponding author for this work

Analytical, Measurements and Physical Chemistry

Oxford University

Research output: Contribution to journal › Article › peer-review

Abstract

Evidence to support an insertion-homolysis mechanism for the event leading to carbon-sulphur bond formation in penicillin biosynthesis has been obtained by a stereochemical probe.

Original language	English
Pages (from-to)	856-858
Number of pages	3
Journal	Journal of the Chemical Society, Chemical Communications
Issue number	13
DOIs	https://doi.org/10.1039/C39910000856
Publication status	Published - 1991

Keywords

penicillin derivative
article
biosynthesis
reaction analysis

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10.1039/C39910000856

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@article{578eb77461a94afc87f1e753d3834afb,

title = "Evidence for an insertion-homolysis mechanism for carbon-sulphur bond formation in penicillin biosynthesis",

abstract = "Evidence to support an insertion-homolysis mechanism for the event leading to carbon-sulphur bond formation in penicillin biosynthesis has been obtained by a stereochemical probe.",

keywords = "penicillin derivative, article, biosynthesis, reaction analysis",

author = "Baldwin, {Jack E.} and Adlington, {Robert M.} and Marquess, {Daniel G.} and Pitt, {Andrew R.} and Russell, {Andrew T.}",

year = "1991",

doi = "10.1039/C39910000856",

language = "English",

pages = "856--858",

journal = "Journal of the Chemical Society, Chemical Communications",

issn = "0022-4936",

publisher = "Chemical Society",

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T1 - Evidence for an insertion-homolysis mechanism for carbon-sulphur bond formation in penicillin biosynthesis

AU - Baldwin, Jack E.

AU - Adlington, Robert M.

AU - Marquess, Daniel G.

AU - Pitt, Andrew R.

AU - Russell, Andrew T.

PY - 1991

Y1 - 1991

N2 - Evidence to support an insertion-homolysis mechanism for the event leading to carbon-sulphur bond formation in penicillin biosynthesis has been obtained by a stereochemical probe.

AB - Evidence to support an insertion-homolysis mechanism for the event leading to carbon-sulphur bond formation in penicillin biosynthesis has been obtained by a stereochemical probe.

KW - penicillin derivative

KW - article

KW - biosynthesis

KW - reaction analysis

UR - http://www.scopus.com/inward/record.url?scp=0025911385&partnerID=8YFLogxK

U2 - 10.1039/C39910000856

DO - 10.1039/C39910000856

M3 - Article

AN - SCOPUS:0025911385

SN - 0022-4936

SP - 856

EP - 858

JO - Journal of the Chemical Society, Chemical Communications

JF - Journal of the Chemical Society, Chemical Communications

IS - 13

ER -

Evidence for an insertion-homolysis mechanism for carbon-sulphur bond formation in penicillin biosynthesis

Abstract

Keywords

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