Fabrication and characterization of electrospun poly-DL-lactide (PDLLA) fibrous coatings on 45S5 Bioglass® substrates for bone tissue engineering applications

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Abstract

BACKGROUND:
This work focuses on combining electrospun biodegradable poly-DL-lactide (PDLLA) fibres and 45S5 Bioglass® for tissue engineering applications.
RESULTS:
A variety of fibrous structures were produced upon application of an electric field to a flowing solution of PDLLA (5 wt/v%) in di-methyl carbonate (DMC). Electrospinning was achieved at an applied voltage of 8.5 kV for a fixed flow rate of 5 μ Lmin-1. Scanning electron microscopy images of PDLLA fibres deposited on 45S5 Bioglass® sintered pellets revealed that the fibres had diameters in the range 100-200 nm, leading to increased surface roughness, as assessed by white light interferometry. Bioactivity studies on PDLLA fibre coated Bioglass® substrates were carried out in simulated body fluid (SBF) for 7, 14 and 28 days. It was found that mineralization of PDLLA fibres on 45S5 Bioglass® substrate (formation of hydroxyapatite) occurred after 7 days of immersion in SBF and full coverage of PDLLA fibres with HA nanocrystals was achieved after 14 days in SBF. CONCLUSION:
The approach investigated represents a convenient method to develop a controlled mineralized fibrous topography on bioactive glass substrates for improved cell attachment, which can be exploited in bone tissue engineering applications.
Original languageEnglish
Pages (from-to)768-774
Number of pages7
JournalJournal of Chemical Technology and Biotechnology
Volume85
Issue number6
DOIs
Publication statusPublished - 27 Oct 2009

Keywords

  • Bioactive glass substrates
  • Bioactivity studies
  • Electrospinning
  • Light interferometry
  • PDLLA fibres
  • SBF
  • Tissue engineering

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