Facile covalent functionalization of graphene oxide using microwaves: Bottom-up development of functional graphitic materials

Manuela Melucci, Emanuele Treossi, Luca Ortolani, Giuliano Giambastiani, Vittorio Morandi, Philipp Klar, Cinzia Casiraghi, Paolo Samorì, Vincenzo Palermo

    Research output: Contribution to journalArticlepeer-review

    Abstract

    Graphene oxide (GO) exfoliated sheets were used as two dimensional platforms to covalently tether on their surface thousands of optically active quaterthiophene molecules (T4), using an innovative microwave-assisted silanization reaction. This method allowed to perform GO functionalization in one-step, under mild conditions in a few tens of minutes rather than days. The hybrid GOT4 could be processed in either H2O or apolar organic solvents and deposited as single sheets, microplatelets or macroscopic membranes. Absorption/emission spectroscopy reveals that GOT4 combines limited T4-T4 interactions with strong T4-GO ones. These findings, combined with the 'user-friendly' engineering approach presented here, pave the way towards the bottom-up fabrication of new GO-based tailored materials for electronics, sensors and biological applications. © 2010 The Royal Society of Chemistry.
    Original languageEnglish
    Pages (from-to)9052-9060
    Number of pages8
    JournalJournal of Materials Chemistry
    Volume20
    Issue number41
    DOIs
    Publication statusPublished - 7 Nov 2010

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