Facile route to conformal hydrotalcite coatings over complex architectures: A hierarchically ordered nanoporous base catalyst for FAME production

Julia J. Creasey; Christopher M A Parlett; Jinesh C. Manayil; Mark A. Isaacs; K. Wilson; Adam F. Lee

doi:10.1039/c4gc01689k

Facile route to conformal hydrotalcite coatings over complex architectures: A hierarchically ordered nanoporous base catalyst for FAME production

Julia J. Creasey, Christopher M A Parlett, Jinesh C. Manayil, Mark A. Isaacs, K. Wilson, Adam F. Lee^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

Abstract

An alkali- and nitrate-free hydrotalcite coating has been grafted onto the surface of a hierarchically ordered macroporous-mesoporous SBA-15 template via stepwise growth of conformal alumina adlayers and their subsequent reaction with magnesium methoxide. The resulting low dimensional hydrotalcite crystallites exhibit excellent per site activity for the base catalysed transesterification of glyceryl triolein with methanol for FAME production.

Original language	English
Pages (from-to)	2398-2405
Number of pages	8
Journal	Green Chemistry
Volume	17
Issue number	4
DOIs	https://doi.org/10.1039/c4gc01689k
Publication status	Published - 1 Apr 2015

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abstract = "An alkali- and nitrate-free hydrotalcite coating has been grafted onto the surface of a hierarchically ordered macroporous-mesoporous SBA-15 template via stepwise growth of conformal alumina adlayers and their subsequent reaction with magnesium methoxide. The resulting low dimensional hydrotalcite crystallites exhibit excellent per site activity for the base catalysed transesterification of glyceryl triolein with methanol for FAME production.",

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T2 - A hierarchically ordered nanoporous base catalyst for FAME production

AU - Creasey, Julia J.

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AU - Manayil, Jinesh C.

AU - Isaacs, Mark A.

AU - Wilson, K.

AU - Lee, Adam F.

PY - 2015/4/1

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AB - An alkali- and nitrate-free hydrotalcite coating has been grafted onto the surface of a hierarchically ordered macroporous-mesoporous SBA-15 template via stepwise growth of conformal alumina adlayers and their subsequent reaction with magnesium methoxide. The resulting low dimensional hydrotalcite crystallites exhibit excellent per site activity for the base catalysed transesterification of glyceryl triolein with methanol for FAME production.

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DO - 10.1039/c4gc01689k

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Facile route to conformal hydrotalcite coatings over complex architectures: A hierarchically ordered nanoporous base catalyst for FAME production

Abstract

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