Fluoroalkenyl, fluoroalkynyl and fluoroalkyl phosphines

Kulbinder K. Banger; Alan K. Brisdon; Christopher J. Herbert; Hana Ali Ghaba; Ian S. Tidmarsh

doi:10.1016/j.jfluchem.2009.08.003

Fluoroalkenyl, fluoroalkynyl and fluoroalkyl phosphines

Kulbinder K. Banger, Alan K. Brisdon, Christopher J. Herbert, Hana Ali Ghaba, Ian S. Tidmarsh

Research output: Contribution to journal › Article › peer-review

Abstract

A review of the methods available for the preparation of monodentate P(III) compounds containing fluoroalkenyl, fluoroalkynyl and fluoroalkyl groups is given. The synthesis, properties and coordination chemistry of some fluoroalkenyl- and fluoroalkynyl-containing phosphines derived from HFC-134a (CF3CH2F) and HFC-245fa (CF3CH2CH2F) is summarised. The development of the reaction between trimethylsilyl-containing phosphines and RfI which provides a general method by which bulky fluoroalkyl groups, such as i-C3F7, t-C4F9, c-C6F11, can be readily introduced into phosphorus(III) centres is reported. Together these methods provide a way of generating P(III) systems of the type R3-nP(Rf)n capable of possessing a wide range of steric and electronic properties. © 2009 Elsevier B.V. All rights reserved.

Original language	English
Pages (from-to)	1117-1129
Number of pages	12
Journal	Journal of Fluorine Chemistry
Volume	130
Issue number	12
DOIs	https://doi.org/10.1016/j.jfluchem.2009.08.003
Publication status	Published - Dec 2009

Keywords

Characterisation
Fluoroalkenyl
Fluoroalkyl
Fluoroalkynyl
Phosphines
Synthesis

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10.1016/j.jfluchem.2009.08.003

CCDC 732140: Experimental Crystal Structure Determination
Banger, K. K. (Contributor), Brisdon, A. (Contributor), Herbert, C. J. (Contributor), Ghaba, H. A. (Contributor) & Tidmarsh, I. S. (Contributor), Cambridge Crystallographic Data Centre, 1 Jan 2010
DOI: 10.5517/ccskvfl, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/ccskvfl&sid=DataCite
Dataset
CCDC 732138: Experimental Crystal Structure Determination
Banger, K. K. (Contributor), Brisdon, A. (Contributor), Herbert, C. J. (Contributor), Ghaba, H. A. (Contributor) & Tidmarsh, I. S. (Contributor), Cambridge Crystallographic Data Centre, 1 Jan 2010
DOI: 10.5517/ccskvcj, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/ccskvcj&sid=DataCite
Dataset
CCDC 732139: Experimental Crystal Structure Determination
Banger, K. K. (Contributor), Brisdon, A. (Contributor), Herbert, C. J. (Contributor), Ghaba, H. A. (Contributor) & Tidmarsh, I. S. (Contributor), Cambridge Crystallographic Data Centre, 1 Jan 2010
DOI: 10.5517/ccskvdk, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/ccskvdk&sid=DataCite
Dataset

Cite this

@article{283a419a76b04787a60842c101bdb7e8,

title = "Fluoroalkenyl, fluoroalkynyl and fluoroalkyl phosphines",

abstract = "A review of the methods available for the preparation of monodentate P(III) compounds containing fluoroalkenyl, fluoroalkynyl and fluoroalkyl groups is given. The synthesis, properties and coordination chemistry of some fluoroalkenyl- and fluoroalkynyl-containing phosphines derived from HFC-134a (CF3CH2F) and HFC-245fa (CF3CH2CH2F) is summarised. The development of the reaction between trimethylsilyl-containing phosphines and RfI which provides a general method by which bulky fluoroalkyl groups, such as i-C3F7, t-C4F9, c-C6F11, can be readily introduced into phosphorus(III) centres is reported. Together these methods provide a way of generating P(III) systems of the type R3-nP(Rf)n capable of possessing a wide range of steric and electronic properties. {\textcopyright} 2009 Elsevier B.V. All rights reserved.",

keywords = "Characterisation, Fluoroalkenyl, Fluoroalkyl, Fluoroalkynyl, Phosphines, Synthesis",

author = "Banger, {Kulbinder K.} and Brisdon, {Alan K.} and Herbert, {Christopher J.} and Ghaba, {Hana Ali} and Tidmarsh, {Ian S.}",

year = "2009",

month = dec,

doi = "10.1016/j.jfluchem.2009.08.003",

language = "English",

volume = "130",

pages = "1117--1129",

journal = "Journal of Fluorine Chemistry",

issn = "0022-1139",

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TY - JOUR

T1 - Fluoroalkenyl, fluoroalkynyl and fluoroalkyl phosphines

AU - Banger, Kulbinder K.

AU - Brisdon, Alan K.

AU - Herbert, Christopher J.

AU - Ghaba, Hana Ali

AU - Tidmarsh, Ian S.

PY - 2009/12

Y1 - 2009/12

N2 - A review of the methods available for the preparation of monodentate P(III) compounds containing fluoroalkenyl, fluoroalkynyl and fluoroalkyl groups is given. The synthesis, properties and coordination chemistry of some fluoroalkenyl- and fluoroalkynyl-containing phosphines derived from HFC-134a (CF3CH2F) and HFC-245fa (CF3CH2CH2F) is summarised. The development of the reaction between trimethylsilyl-containing phosphines and RfI which provides a general method by which bulky fluoroalkyl groups, such as i-C3F7, t-C4F9, c-C6F11, can be readily introduced into phosphorus(III) centres is reported. Together these methods provide a way of generating P(III) systems of the type R3-nP(Rf)n capable of possessing a wide range of steric and electronic properties. © 2009 Elsevier B.V. All rights reserved.

AB - A review of the methods available for the preparation of monodentate P(III) compounds containing fluoroalkenyl, fluoroalkynyl and fluoroalkyl groups is given. The synthesis, properties and coordination chemistry of some fluoroalkenyl- and fluoroalkynyl-containing phosphines derived from HFC-134a (CF3CH2F) and HFC-245fa (CF3CH2CH2F) is summarised. The development of the reaction between trimethylsilyl-containing phosphines and RfI which provides a general method by which bulky fluoroalkyl groups, such as i-C3F7, t-C4F9, c-C6F11, can be readily introduced into phosphorus(III) centres is reported. Together these methods provide a way of generating P(III) systems of the type R3-nP(Rf)n capable of possessing a wide range of steric and electronic properties. © 2009 Elsevier B.V. All rights reserved.

KW - Characterisation

KW - Fluoroalkenyl

KW - Fluoroalkyl

KW - Fluoroalkynyl

KW - Phosphines

KW - Synthesis

U2 - 10.1016/j.jfluchem.2009.08.003

DO - 10.1016/j.jfluchem.2009.08.003

M3 - Article

SN - 0022-1139

VL - 130

SP - 1117

EP - 1129

JO - Journal of Fluorine Chemistry

JF - Journal of Fluorine Chemistry

IS - 12

ER -

Fluoroalkenyl, fluoroalkynyl and fluoroalkyl phosphines

Abstract

Keywords

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Datasets

CCDC 732140: Experimental Crystal Structure Determination

CCDC 732138: Experimental Crystal Structure Determination

CCDC 732139: Experimental Crystal Structure Determination

Cite this