Formation of a new class of 7π radicals via sterically induced P-P bond cleavage of the dimers [(CH)2(NR)2P]2

Ruth Edge; Robert J. Less; Eric J L McInnes; Kristine Müther; Vesal Naseri; Jeremy M. Rawson; Dominic S. Wright

doi:10.1039/b821241d

Formation of a new class of 7π radicals via sterically induced P-P bond cleavage of the dimers [(CH)2(NR)2P]2

Ruth Edge, Robert J. Less, Eric J L McInnes, Kristine Müther, Vesal Naseri, Jeremy M. Rawson, Dominic S. Wright

Research output: Contribution to journal › Article › peer-review

Abstract

The 2c-2e- P-P bonded dimers [(CH)2(NR) 2P]2 dissociate in solution to give the persistent new 7π radicals [(CH)2(NR)2P]•, which are isoelectronic with the well known S/N thiazolyl radicals. © The Royal Society of Chemistry.

Original language	English
Pages (from-to)	1691-1693
Number of pages	2
Journal	Chemical Communications
Issue number	13
DOIs	https://doi.org/10.1039/b821241d
Publication status	Published - 2009

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10.1039/b821241d

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@article{02c3b36829ae41ee8577f361a75b23a7,

title = "Formation of a new class of 7π radicals via sterically induced P-P bond cleavage of the dimers [(CH)2(NR)2P]2",

abstract = "The 2c-2e- P-P bonded dimers [(CH)2(NR) 2P]2 dissociate in solution to give the persistent new 7π radicals [(CH)2(NR)2P]•, which are isoelectronic with the well known S/N thiazolyl radicals. {\textcopyright} The Royal Society of Chemistry.",

author = "Ruth Edge and Less, \{Robert J.\} and McInnes, \{Eric J L\} and Kristine M{\"u}ther and Vesal Naseri and Rawson, \{Jeremy M.\} and Wright, \{Dominic S.\}",

year = "2009",

doi = "10.1039/b821241d",

language = "English",

pages = "1691--1693",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

number = "13",

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TY - JOUR

T1 - Formation of a new class of 7π radicals via sterically induced P-P bond cleavage of the dimers [(CH)2(NR)2P]2

AU - Edge, Ruth

AU - Less, Robert J.

AU - McInnes, Eric J L

AU - Müther, Kristine

AU - Naseri, Vesal

AU - Rawson, Jeremy M.

AU - Wright, Dominic S.

PY - 2009

Y1 - 2009

N2 - The 2c-2e- P-P bonded dimers [(CH)2(NR) 2P]2 dissociate in solution to give the persistent new 7π radicals [(CH)2(NR)2P]•, which are isoelectronic with the well known S/N thiazolyl radicals. © The Royal Society of Chemistry.

AB - The 2c-2e- P-P bonded dimers [(CH)2(NR) 2P]2 dissociate in solution to give the persistent new 7π radicals [(CH)2(NR)2P]•, which are isoelectronic with the well known S/N thiazolyl radicals. © The Royal Society of Chemistry.

UR - https://www.scopus.com/pages/publications/62349096202

U2 - 10.1039/b821241d

DO - 10.1039/b821241d

M3 - Article

SN - 1359-7345

SP - 1691

EP - 1693

JO - Chemical Communications

JF - Chemical Communications

IS - 13

ER -

Formation of a new class of 7π radicals via sterically induced P-P bond cleavage of the dimers [(CH)2(NR)2P]2

Abstract

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CCDC 707576: Experimental Crystal Structure Determination

CCDC 707575: Experimental Crystal Structure Determination

CCDC 707574: Experimental Crystal Structure Determination

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Formation of a new class of 7π radicals via sterically induced P-P bond cleavage of the dimers [(CH)2(NR)2P]2

Abstract

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Datasets

CCDC 707576: Experimental Crystal Structure Determination

CCDC 707575: Experimental Crystal Structure Determination

CCDC 707574: Experimental Crystal Structure Determination

Cite this