Formation of an Interlocked Double-Chain from an Organic-Inorganic [2]Rotaxane

Jesus Ferrando-soria; Antonio Fernandez; Inigo Vitorica-yrzebal; Deepak Asthana; Christopher Muryn; Floriana Tuna; Grigore A. Timco; Richard E. P. Winpenny

doi:10.1039/C8CC09339C

Formation of an Interlocked Double-Chain from an Organic-Inorganic [2]Rotaxane

Jesus Ferrando-soria, Antonio Fernandez, Inigo Vitorica-yrzebal, Deepak Asthana, Christopher Muryn, Floriana Tuna, Grigore A. Timco, Richard E. P. Winpenny

Research output: Contribution to journal › Article › peer-review

Abstract

Here we show that a structure containing a polymeric interlocking daisy chain is obtained from the reaction of an inorganic–organic [2]rotaxane [H B {CrIII7Ni II (μ-F) 8 (O 2 C t Bu) 16 }], where B is an organic thread terminated with a bi-pyridyl unit, with an oxo-centered metal carboxylate triangle [FeIII2Co II (μ 3 -O)(O 2 C t Bu) 6 (HO 2 C t Bu) 3 ]. Here we show that a structure containing a polymeric interlocking daisy chain is obtained from the reaction of an inorganic–organic [2]rotaxane [H B {CrIII7Ni II (μ-F) 8 (O 2 C t Bu) 16 }], where B is an organic thread terminated with a bi-pyridyl unit, with an oxo-centered metal carboxylate triangle [FeIII2Co II (μ 3 -O)(O 2 C t Bu) 6 (HO 2 C t Bu) 3 ].

Original language	English
Pages (from-to)	2960-2963
Number of pages	4
Journal	Chemical Communications
Volume	55
Issue number	20
Early online date	11 Feb 2019
DOIs	https://doi.org/10.1039/C8CC09339C
Publication status	Published - 2019

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10.1039/C8CC09339C

EPSRC National Research Facility for Electron Paramagnetic Resonance
Collison, D. (Academic lead), Mcinnes, E. (Academic lead), Tuna, F. (Academic lead), Bowen, A. (Academic lead), Shanmugam, M. (Senior Technical Specialist), Brookfield, A. (Technical Specialist), Fleming, E. (Other) & Cliff, M. (Platform Lead)
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@article{b19f9a09b97742e3a0620193f51ff1da,

title = "Formation of an Interlocked Double-Chain from an Organic-Inorganic [2]Rotaxane",

abstract = " Here we show that a structure containing a polymeric interlocking daisy chain is obtained from the reaction of an inorganic–organic [2]rotaxane [H B {CrIII7Ni II (μ-F) 8 (O 2 C t Bu) 16 }], where B is an organic thread terminated with a bi-pyridyl unit, with an oxo-centered metal carboxylate triangle [FeIII2Co II (μ 3 -O)(O 2 C t Bu) 6 (HO 2 C t Bu) 3 ]. Here we show that a structure containing a polymeric interlocking daisy chain is obtained from the reaction of an inorganic–organic [2]rotaxane [H B {CrIII7Ni II (μ-F) 8 (O 2 C t Bu) 16 }], where B is an organic thread terminated with a bi-pyridyl unit, with an oxo-centered metal carboxylate triangle [FeIII2Co II (μ 3 -O)(O 2 C t Bu) 6 (HO 2 C t Bu) 3 ]. ",

author = "Jesus Ferrando-soria and Antonio Fernandez and Inigo Vitorica-yrzebal and Deepak Asthana and Christopher Muryn and Floriana Tuna and Timco, {Grigore A.} and Winpenny, {Richard E. P.}",

year = "2019",

doi = "10.1039/C8CC09339C",

language = "English",

volume = "55",

pages = "2960--2963",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

number = "20",

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TY - JOUR

T1 - Formation of an Interlocked Double-Chain from an Organic-Inorganic [2]Rotaxane

AU - Ferrando-soria, Jesus

AU - Fernandez, Antonio

AU - Vitorica-yrzebal, Inigo

AU - Asthana, Deepak

AU - Muryn, Christopher

AU - Tuna, Floriana

AU - Timco, Grigore A.

AU - Winpenny, Richard E. P.

PY - 2019

Y1 - 2019

N2 - Here we show that a structure containing a polymeric interlocking daisy chain is obtained from the reaction of an inorganic–organic [2]rotaxane [H B {CrIII7Ni II (μ-F) 8 (O 2 C t Bu) 16 }], where B is an organic thread terminated with a bi-pyridyl unit, with an oxo-centered metal carboxylate triangle [FeIII2Co II (μ 3 -O)(O 2 C t Bu) 6 (HO 2 C t Bu) 3 ]. Here we show that a structure containing a polymeric interlocking daisy chain is obtained from the reaction of an inorganic–organic [2]rotaxane [H B {CrIII7Ni II (μ-F) 8 (O 2 C t Bu) 16 }], where B is an organic thread terminated with a bi-pyridyl unit, with an oxo-centered metal carboxylate triangle [FeIII2Co II (μ 3 -O)(O 2 C t Bu) 6 (HO 2 C t Bu) 3 ].

AB - Here we show that a structure containing a polymeric interlocking daisy chain is obtained from the reaction of an inorganic–organic [2]rotaxane [H B {CrIII7Ni II (μ-F) 8 (O 2 C t Bu) 16 }], where B is an organic thread terminated with a bi-pyridyl unit, with an oxo-centered metal carboxylate triangle [FeIII2Co II (μ 3 -O)(O 2 C t Bu) 6 (HO 2 C t Bu) 3 ]. Here we show that a structure containing a polymeric interlocking daisy chain is obtained from the reaction of an inorganic–organic [2]rotaxane [H B {CrIII7Ni II (μ-F) 8 (O 2 C t Bu) 16 }], where B is an organic thread terminated with a bi-pyridyl unit, with an oxo-centered metal carboxylate triangle [FeIII2Co II (μ 3 -O)(O 2 C t Bu) 6 (HO 2 C t Bu) 3 ].

U2 - 10.1039/C8CC09339C

DO - 10.1039/C8CC09339C

M3 - Article

SN - 1359-7345

VL - 55

SP - 2960

EP - 2963

JO - Chemical Communications

JF - Chemical Communications

IS - 20

ER -

Formation of an Interlocked Double-Chain from an Organic-Inorganic [2]Rotaxane

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