Formation of octapod MnO nanoparticles with enhanced magnetic properties through kinetically-controlled thermal decomposition of polynuclear manganese complexes

Fraser J. Douglas, Donald A. Maclaren, Floriana Tuna, William M. Holmes, Catherine C. Berry, Mark Murrie

    Research output: Contribution to journalArticlepeer-review

    Abstract

    Polynuclear manganese complexes are used as precursors for the synthesis of manganese oxide nanoparticles (MnO NPs). Altering the thermal decomposition conditions can shift the nanoparticle product from spherical, thermodynamically-driven NPs to unusual, kinetically-controlled octapod structures. The resulting increased surface area profoundly alters the NP's surface-dependent magnetism and may have applications in nanomedicine. © 2014 The Royal Society of Chemistry.
    Original languageEnglish
    Pages (from-to)172-176
    Number of pages4
    JournalNanoscale
    Volume6
    Issue number1
    DOIs
    Publication statusPublished - 7 Jan 2014

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