Formation of Porous Anodic Oxide Film on Titanium in Phosphoric Acid Electrolyte

Z. Liu; G.E. Thompson

doi:10.1007/s11665-014-1262-7

Formation of Porous Anodic Oxide Film on Titanium in Phosphoric Acid Electrolyte

Z. Liu, G.E. Thompson

The University of Manchester

Research output: Contribution to journal › Article › peer-review

Abstract

A sequential breakdown anodizing conditions on cp-Ti in phosphoric acid has been investigated in the present study. Anodic oxide films were formed at 100, 150, and 200 V, examined by scanning electron microscopy, Raman spectroscopy, glow discharge optical emission spectrometry, and electrochemical impedance spectroscopy. A porous oxide texture was formed at each voltage. The thickness of anodic porous oxide increased with the increase of anodic voltage. Nano-particulates were formed around and within the pores, and the size of pores increased with increased voltage due to the expansion of particulates. The amorphous-to-crystalline transition was initiated during the film growth. The degree of crystallinity in the anodic oxide film fabricated at 200 V is more abundant than 150 and 100 V. Increased content of the phosphorus species was incorporated into the porous film with the increase of anodic voltage, stabilizing for the nanocrystals developed within the oxide.

Original language	English
Pages (from-to)	59-66
Number of pages	7
Journal	Journal of Materials Engineering and Performance
Volume	24
DOIs	https://doi.org/10.1007/s11665-014-1262-7
Publication status	Published - 15 Oct 2014

Keywords

breakdown voltage, crystallization, oxygen evolution, phosphoric acid, porous oxide film

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10.1007/s11665-014-1262-7

Light Alloys towards environmentally sustainable transport: 2nd generation solutions for Advanced Metallic Systems ( LATEST 2 )
Thompson, G. (PI), Bate, P. (CoI), Prangnell, P. (CoI), Preuss, M. (CoI), Quinta Da Fonseca, J. (CoI), Robson, J. (CoI), Skeldon, P. (CoI) & Zhou, X. (CoI)
1/02/10 → 31/07/15
Project: Research

Cite this

@article{79b3cdb0a0d0450c8847b9e6788d150f,

title = "Formation of Porous Anodic Oxide Film on Titanium in Phosphoric Acid Electrolyte",

abstract = "A sequential breakdown anodizing conditions on cp-Ti in phosphoric acid has been investigated in the present study. Anodic oxide films were formed at 100, 150, and 200 V, examined by scanning electron microscopy, Raman spectroscopy, glow discharge optical emission spectrometry, and electrochemical impedance spectroscopy. A porous oxide texture was formed at each voltage. The thickness of anodic porous oxide increased with the increase of anodic voltage. Nano-particulates were formed around and within the pores, and the size of pores increased with increased voltage due to the expansion of particulates. The amorphous-to-crystalline transition was initiated during the film growth. The degree of crystallinity in the anodic oxide film fabricated at 200 V is more abundant than 150 and 100 V. Increased content of the phosphorus species was incorporated into the porous film with the increase of anodic voltage, stabilizing for the nanocrystals developed within the oxide.",

keywords = "breakdown voltage, crystallization, oxygen evolution, phosphoric acid, porous oxide film",

author = "Z. Liu and G.E. Thompson",

note = "The author is grateful for the support for this work from the Corrosion and Protection Centre, The University of Manchester, UK. Special thanks to Prof. G.E. Thompson for supervising and facilitating the critical resources for the study; Prof. P. Skeldon for his assistance with critical discussion; and Dr. H. Liu for providing access to the GDOES instrument and also his insight into the result analysis. The authors also thank of the Engineering and Physical Science Research Council (UK) for financial support (Programme Grant: LATEST2).",

year = "2014",

month = oct,

day = "15",

doi = "10.1007/s11665-014-1262-7",

language = "English",

volume = "24",

pages = "59--66",

journal = "Journal of Materials Engineering and Performance",

issn = "1059-9495",

publisher = "Springer New York",

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TY - JOUR

T1 - Formation of Porous Anodic Oxide Film on Titanium in Phosphoric Acid Electrolyte

AU - Liu, Z.

AU - Thompson, G.E.

N1 - The author is grateful for the support for this work from the Corrosion and Protection Centre, The University of Manchester, UK. Special thanks to Prof. G.E. Thompson for supervising and facilitating the critical resources for the study; Prof. P. Skeldon for his assistance with critical discussion; and Dr. H. Liu for providing access to the GDOES instrument and also his insight into the result analysis. The authors also thank of the Engineering and Physical Science Research Council (UK) for financial support (Programme Grant: LATEST2).

PY - 2014/10/15

Y1 - 2014/10/15

N2 - A sequential breakdown anodizing conditions on cp-Ti in phosphoric acid has been investigated in the present study. Anodic oxide films were formed at 100, 150, and 200 V, examined by scanning electron microscopy, Raman spectroscopy, glow discharge optical emission spectrometry, and electrochemical impedance spectroscopy. A porous oxide texture was formed at each voltage. The thickness of anodic porous oxide increased with the increase of anodic voltage. Nano-particulates were formed around and within the pores, and the size of pores increased with increased voltage due to the expansion of particulates. The amorphous-to-crystalline transition was initiated during the film growth. The degree of crystallinity in the anodic oxide film fabricated at 200 V is more abundant than 150 and 100 V. Increased content of the phosphorus species was incorporated into the porous film with the increase of anodic voltage, stabilizing for the nanocrystals developed within the oxide.

AB - A sequential breakdown anodizing conditions on cp-Ti in phosphoric acid has been investigated in the present study. Anodic oxide films were formed at 100, 150, and 200 V, examined by scanning electron microscopy, Raman spectroscopy, glow discharge optical emission spectrometry, and electrochemical impedance spectroscopy. A porous oxide texture was formed at each voltage. The thickness of anodic porous oxide increased with the increase of anodic voltage. Nano-particulates were formed around and within the pores, and the size of pores increased with increased voltage due to the expansion of particulates. The amorphous-to-crystalline transition was initiated during the film growth. The degree of crystallinity in the anodic oxide film fabricated at 200 V is more abundant than 150 and 100 V. Increased content of the phosphorus species was incorporated into the porous film with the increase of anodic voltage, stabilizing for the nanocrystals developed within the oxide.

KW - breakdown voltage, crystallization, oxygen evolution, phosphoric acid, porous oxide film

U2 - 10.1007/s11665-014-1262-7

DO - 10.1007/s11665-014-1262-7

M3 - Article

SN - 1059-9495

VL - 24

SP - 59

EP - 66

JO - Journal of Materials Engineering and Performance

JF - Journal of Materials Engineering and Performance

ER -

Formation of Porous Anodic Oxide Film on Titanium in Phosphoric Acid Electrolyte

Abstract

Keywords

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Light Alloys towards environmentally sustainable transport: 2nd generation solutions for Advanced Metallic Systems ( LATEST 2 )

Cite this