Gamma irradiation resistance of an early age slag-​blended cement matrix for nuclear waste encapsulation

Neda Mobasher, Susan A Bernal, Hajime Kinoshita, Clint Alan Sharrad, John L Provis

    Research output: Contribution to journalArticlepeer-review

    Abstract

    Irradiation is one of the characteristic conditions that nuclear wasteforms must withstand to assure integrity during their service life. This study investigates gamma irradiation resistance of an earlyage slag cement-based grout, which is of interest for the nuclear industry as it is internationally used for encapsulation of low and intermediate level radioactive wastes. The slag cement-based grout withstands a gamma irradiation dose of 4.77 MGy over 256 h without reduction in its compressive strength; however, some cracking of irradiated samples was identified. The high strength retention is associated with the fact that the main hydration product forming in this binder, a calcium aluminum silicate hydrate (C–A–S–H) type gel, remains unmodified upon irradiation. Comparison with a heat-treated sample was carried out to identify potential effects of the temperature rise during irradiation exposure. The results suggested that formation of cracks is a combined effect of radiolysis and heating upon irradiation exposure.
    Original languageEnglish
    Pages (from-to)1563-1571
    Number of pages8
    JournalJournal of Materials Research
    Volume30
    Issue number9
    DOIs
    Publication statusPublished - 14 May 2015

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