Generation of benzyne from benzoic acid using C-H activation

Alastair A. Cant; Lee Roberts; Michael F. Greaney

doi:10.1039/c0cc02547j

Generation of benzyne from benzoic acid using C-H activation

Alastair A. Cant, Lee Roberts, Michael F. Greaney

Research output: Contribution to journal › Article › peer-review

Abstract

ortho C-H activation of benzoic acids with Pd(ii) generates an oxapalladacycle that can decarboxylate to produce a palladium-associated aryne. The arynes then undergo [2+2+2] trimerisation to afford triphenylenes. © 2010 The Royal Society of Chemistry.

Original language	English
Pages (from-to)	8671-8673
Number of pages	2
Journal	Chemical Communications
Volume	46
Issue number	45
DOIs	https://doi.org/10.1039/c0cc02547j
Publication status	Published - 7 Dec 2010

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title = "Generation of benzyne from benzoic acid using C-H activation",

abstract = "ortho C-H activation of benzoic acids with Pd(ii) generates an oxapalladacycle that can decarboxylate to produce a palladium-associated aryne. The arynes then undergo [2+2+2] trimerisation to afford triphenylenes. {\textcopyright} 2010 The Royal Society of Chemistry.",

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AU - Cant, Alastair A.

AU - Roberts, Lee

AU - Greaney, Michael F.

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AB - ortho C-H activation of benzoic acids with Pd(ii) generates an oxapalladacycle that can decarboxylate to produce a palladium-associated aryne. The arynes then undergo [2+2+2] trimerisation to afford triphenylenes. © 2010 The Royal Society of Chemistry.

U2 - 10.1039/c0cc02547j

DO - 10.1039/c0cc02547j

M3 - Article

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JO - Chemical Communications

JF - Chemical Communications

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ER -

Generation of benzyne from benzoic acid using C-H activation

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